From 1D ordered linear polymers to discrete macrocycles: surface adsorption and pH take control

被引:5
作者
Cao, Lili [1 ]
Yu, Yanxia [1 ]
Lei, Shengbin [1 ,2 ]
机构
[1] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150080, Heilongjiang, Peoples R China
[2] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn, Tianjin Key Lab Mol Optoelect Sci, Dept Chem,Sch Sci, Tianjin 300072, Peoples R China
基金
美国国家科学基金会;
关键词
DYNAMIC COVALENT CHEMISTRY; ORGANIC FRAMEWORKS; AQUEOUS-SOLUTION;
D O I
10.1039/c8cc06036c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work we demonstrate that the surface adsorption and pH play a determining role in controlling the final product of a Schiff base reaction. Either 1D linear polymers or discrete macrocycles can be obtained by tuning the pH and surface confinement.
引用
收藏
页码:12210 / 12213
页数:4
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