The first example of sulfinatodehalogenation of 2,2,2-trifluoroethyl halides: A novel method for trifluoroethylation of alkenes and alkynes

被引：49

作者：

Long, ZY ^{[1
]}

Chen, QY ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Lab Fluorine Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 46期

基金：

中国国家自然科学基金;

关键词：

2,2,2-trifluoroethyl halides; trifluoroethylation; alkenes; alkynes;

D O I：

10.1016/S0040-4039(98)01906-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,2,2-Trifluoroethylation of alkenes and alkynes with 2,2,2-trifluoroethyl iodide or bromide and sodium dithionite in DMSO or CH3CN/H2O can occur under mild conditions. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8487 / 8490

页数：4

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