Relativistic effects in PtF6 and isoelectronic octahedral groups:: Magnetic susceptibility, 19F NMR, and ab initio calculations

被引：12

作者：

Gabuda, SP ^{[1
]}

Ikorskii, VN ^{[1
]}

Kozlova, SG ^{[1
]}

Nikitin, PS ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

JETP LETTERS | 2001年 / 73卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/1.1355403

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The temperature-independent paramagnetism and high O-h symmetry of PtF6 molecules in solids (at 77 K) and of the octahedral molecular complexes [IrF6](-) in KIrF6 and [OsF6](2-) in K2OsF6 are shown to be consistent with the model of strong spin-orbit coupling of 5d(4) electrons. (C) 2001 MAIK "Nauka/Interperiodica".

引用

页码：35 / 38

页数：4

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