Synthesis of polymer-silica hybrid microparticles with defined geometry using surface initiated atom transfer radical polymerization

被引：3
作者：
Lang, Y. [1 ,2 ,3 ]
del Monte, F. [4 ]
Finn, D. P. [2 ,3 ]
Wang, W. [1 ]
Pandit, A. [1 ]
机构：
[1] Natl Univ Ireland, Network Excellence Funct Biomat, Galway, Ireland
[2] Natl Univ Ireland, Sch Med, Pharmacol & Therapeut, Galway, Ireland
[3] Natl Univ Ireland, Ctr Pain Res, Galway, Ireland
[4] CSIC, Inst Ciencia Mat, Madrid, Spain
来源：
POLYMER CHEMISTRY | 2015年 / 6卷 / 16期
基金：
爱尔兰科学基金会;
关键词：
METHYL-METHACRYLATE; MARINE DIATOM; SI-ATRP; NANOPARTICLES; POLYSTYRENE; PARTICLES; FUNCTIONALIZATION; TEMPERATURE; BIOSILICA;
D O I：
10.1039/c5py00228a
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Nanostructured polymer/silica hybrid materials have gained attention as they combine the advantageous properties of organic and inorganic materials in one entity. Herein, we report incorporation of chloromethyl moieties into a living diatom to prepare an alkyl-halide activated siliceous biotemplate. Subsequent, in situ polymerization via surface initiated atom transfer radical polymerization generated a polymer/silica microparticle with defined geometry.
引用
收藏
页码：3014 / 3017
页数：4
相关论文
共 50 条
  • [41] Synthesis of Polymer/Silica Hybrid Nanoparticles Using Anionic Polymerization Techniques
    Huebner, Eike
    Allgaier, Juergen
    Meyer, Mathias
    Stellbrink, Joerg
    Pyckhout-Hintzen, Wim
    Richter, Dieter
    MACROMOLECULES, 2010, 43 (02) : 856 - 867
  • [42] Synthesis and properties of organic/inorganic hybrid nanoparticles prepared using atom transfer radical polymerization
    Wang, Tzong-Liu
    Ou, Chia-Chih
    Yang, Chien-Hsin
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (05) : 3421 - 3430
  • [43] Synthesis of well-defined polystyrene macrophotoinitiators by atom-transfer radical polymerization
    Degirmenci, M
    Cianga, I
    Yagci, Y
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2002, 203 (10-11) : 1279 - 1284
  • [44] Well-defined hydroxyapatite-polycation nanohybrids via surface-initiated atom transfer radical polymerization for biomedical applications
    Cai, Q.
    Zhu, Y.
    He, J. Q.
    Wang, Z. H.
    Su, Fabing
    Xu, F. J.
    Yang, X. P.
    Yang, W. T.
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) : 9358 - 9367
  • [45] Inorganic/Organic Core-Shell Composite Nanoparticles by Surface-Initiated Atom Transfer Radical Polymerization
    Chen Siyuan
    Dong Xu
    Zha Liusheng
    PROGRESS IN CHEMISTRY, 2015, 27 (07) : 831 - 840
  • [46] Redox-Responsive Polymer Brushes Grafted from Polystyrene Nanoparticles by Means of Surface Initiated Atom Transfer Radical Polymerization
    Mazurowski, Markus
    Gallei, Markus
    Li, Junyu
    Didzoleit, Haiko
    Stuehn, Bernd
    Rehahn, Matthias
    MACROMOLECULES, 2012, 45 (22) : 8970 - 8981
  • [47] A generalizable method for the construction of MOF@polymer functional composites through surface-initiated atom transfer radical polymerization
    He, Sanfeng
    Wang, Hongliang
    Zhang, Cuizheng
    Zhang, Songwei
    Yu, Yi
    Lee, Yongjin
    Li, Tao
    CHEMICAL SCIENCE, 2019, 10 (06) : 1816 - 1822
  • [48] Confining polymerization at emulsion interface by surface-initiated atom transfer radical polymerization on reactive Pickering stabilizer
    Yin, Dezhong
    Geng, Wangchang
    Zhang, Qiuyu
    Zhang, Baoliang
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 31 : 360 - 366
  • [49] Fabrication of hollow polyelectrolyte nanospheres via surface-initiated atom transfer radical polymerization
    He, Xiaoyan
    Yang, Wu
    Yuan, Li
    Pei, Xiaowei
    Gao, Jinzhang
    MATERIALS LETTERS, 2009, 63 (13-14) : 1138 - 1140
  • [50] Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids
    McDonald, Kyle A.
    Feldblyum, Jeremy I.
    Koh, Kyoungmoo
    Wong-Foy, Antek G.
    Matzger, Adam J.
    CHEMICAL COMMUNICATIONS, 2015, 51 (60) : 11994 - 11996
12345