Synthesis of polymer-silica hybrid microparticles with defined geometry using surface initiated atom transfer radical polymerization

被引：3

作者：

Lang, Y. ^{[1
,2
,3
]}

del Monte, F. ^{[4
]}

Finn, D. P. ^{[2
,3
]}

Wang, W. ^{[1
]}

Pandit, A. ^{[1
]}

机构：

[1] Natl Univ Ireland, Network Excellence Funct Biomat, Galway, Ireland

[2] Natl Univ Ireland, Sch Med, Pharmacol & Therapeut, Galway, Ireland

[3] Natl Univ Ireland, Ctr Pain Res, Galway, Ireland

[4] CSIC, Inst Ciencia Mat, Madrid, Spain

来源：

POLYMER CHEMISTRY | 2015年 / 6卷 / 16期

基金：

爱尔兰科学基金会;

关键词：

METHYL-METHACRYLATE; MARINE DIATOM; SI-ATRP; NANOPARTICLES; POLYSTYRENE; PARTICLES; FUNCTIONALIZATION; TEMPERATURE; BIOSILICA;

D O I：

10.1039/c5py00228a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nanostructured polymer/silica hybrid materials have gained attention as they combine the advantageous properties of organic and inorganic materials in one entity. Herein, we report incorporation of chloromethyl moieties into a living diatom to prepare an alkyl-halide activated siliceous biotemplate. Subsequent, in situ polymerization via surface initiated atom transfer radical polymerization generated a polymer/silica microparticle with defined geometry.

引用

页码：3014 / 3017

页数：4

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