A highly efficient non-heme manganese complex in oxygenation reactions

被引：96
作者：
Nehru, Kasi
Kim, Soo Jeong
Kim, In Young
Seo, Mi Sook
Kim, Youngmee
Kim, Sung-Jin
Kim, Jinheung
Nam, Wonwoo [1 ]
机构：
[1] Ewha Womans Univ, Dept Chem, Div Nano Sci, Seoul 120750, South Korea
[2] Ewha Womans Univ, Ctr Biomimet Syst, Seoul 120750, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 44期
关键词：
D O I：
10.1039/b708976g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.
引用
收藏
页码：4623 / 4625
页数：3
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