Modulation of the mechanical energy storage performance of the MIL-47(VIV) metal organic framework by ligand functionalization

被引：14

作者：

Yot, Pascal G. ^{[1
]}

Wahiduzzaman, Mohammad ^{[1
]}

Elkaim, Erik ^{[2
]}

Fertey, Pierre ^{[2
]}

Fabry, Paul ^{[3
]}

Serre, Christian ^{[4
]}

Maurin, Guillaume ^{[1
]}

机构：

[1] Univ Montpellier, CNRS, UMR 5253, ENSCM,ICGM, CC 1505,Pl Eugene Bataillon, F-34095 Montpellier 05, France

[2] Synchrotron Soleil, BP 48, F-91192 Gif Sur Yvette, France

[3] Univ Versailles St Quentin, CNRS, UMR 8180, Inst Lavoisier Versailles, 45 Ave Etats Unis, F-78035 Versailles, France

[4] PSL Univ, Ecole Super Phys & Chim Ind Paris, Ecole Normale Super Paris, Inst Mat Poreux Paris IMAP,CNRS,FRE 2000, F-75005 Paris, France

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 05期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; PRESSURE; GUEST; MOF; DIFFRACTION; HYBRID; WATER;

D O I：

10.1039/c8dt04214d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The functionalization of the metal-organic framework MIL-47(V-IV) with ligands bearing bulky functional groups (-Br or -CF3) has been envisaged as a possible route to enhance the mechanical energy storage performances of this family of hybrid porous materials. This exploratory work was carried out by coupling advanced experimental techniques (mercury intrusion and X-ray powder diffraction) supported by density functional theory calculations. MIL-47(V-IV)-BDC-CF3 was demonstrated to be one of the most promising porous materials for mechanical energy-related applications with performance in terms of work energy which surpasses that of any porous solids reported so far.

引用

页码：1656 / 1661

页数：6

共 47 条

[1]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[2]

2-Y

[3] Mechanical Properties of Dense Zeolitic Imidazolate Frameworks (ZIFs): A High-Pressure X-ray Diffraction, Nanoindentation and Computational Study of the Zinc Framework Zn(Im)2, and its Lithium-Boron Analogue, LiB(Im)4 [J].

Bennett, Thomas D. ;

Tan, Jin-Chong ;

Moggach, Stephen A. ;

Galvelis, Raimondas ;

Mellot-Draznieks, Caroline ;

Reisner, Barbara A. ;

Thirumurugan, A. ;

Allan, David. R. ;

Cheetham, Anthony K. .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (35) :10684-10690

[4] Using Pressure to Provoke the Structural Transition of Metal-Organic Frameworks [J].

Beurroies, Isabelle ;

Boulhout, Mohammed ;

Llewellyn, Philip L. ;

Kuchta, Bogdan ;

Ferey, Gerard ;

Serre, Christian ;

Denoyel, Renaud .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (41) :7526-7529

[5] New Functionalized Metal-Organic Frameworks MIL-47-X (X = -Cl, -Br, -CH3, -CF3, -OH, -OCH3): Synthesis, Characterization, and CO2 Adsorption Properties [J].

Biswas, Shyam ;

Vanpoucke, Danny E. P. ;

Verstraelen, Toon ;

Vandichel, Matthias ;

Couck, Sarah ;

Leus, Karen ;

Liu, Ying-Ya ;

Waroquier, Michel ;

Van Speybroeck, Veronique ;

Denayer, Joeri F. M. ;

Van der Voort, Pascal .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (44) :22784-22796

[6] INDEXING OF POWDER DIFFRACTION PATTERNS FOR LOW-SYMMETRY LATTICES BY THE SUCCESSIVE DICHOTOMY METHOD [J].

BOULTIF, A ;

LOUER, D .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 (pt 6) :987-993

[7] Modulation of pore shape and adsorption selectivity by ligand functionalization in a series of "rob"-like flexible metal-organic frameworks [J].

Cepeda, Javier ;

Perez-Mendoza, Manuel ;

Calahorro, Antonio J. ;

Casati, Nicola ;

Manuel Seco, Jose ;

Aragones-Anglada, Marta ;

Moghadam, Peyman Z. ;

Fairen-Jimenez, David ;

Rodriguez-Dieguez, Antonio .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (36) :17409-17416

[8] Guest-dependent high pressure phenomena in a nanoporous metal-organic framework material [J].

Chapman, Karena W. ;

Halder, Gregory J. ;

Chupas, Peter J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) :10524-+

[9] Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host-Guest Interactions [J].

Devic, Thomas ;

Horcajada, Patricia ;

Serre, Christian ;

Salles, Fabrice ;

Maurin, Guillaume ;

Moulin, Beatrice ;

Heurtaux, Daniela ;

Clet, Guillaume ;

Vimont, Alexandre ;

Greneche, Jean-Marc ;

Le Ouay, Benjamin ;

Moreau, Florian ;

Magnier, Emmanuel ;

Filinchuk, Yaroslav ;

Marrot, Jerome ;

Lavalley, Jean-Claude ;

Daturi, Marco ;

Ferey, Gerard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) :1127-1136

[10] Energetics: A new field of applications for hydrophobic zeolites [J].

Eroshenko, V ;

Regis, RC ;

Soulard, M ;

Patarin, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (33) :8129-8130

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