Products of sugar beet processing as raw materials for chemicals and biodegradable polymers

被引:88
作者
Tomaszewska, J. [1 ]
Bielinski, D. [2 ]
Binczarski, M. [1 ]
Berlowska, J. [3 ]
Dziugan, P. [3 ]
Piotrowski, J. [4 ]
Stanishevsky, A. [5 ]
Witonska, I. A. [1 ]
机构
[1] Lodz Univ Technol, Inst Gen & Ecol Chem, 116 Zeromskiego St, PL-90924 Lodz, Poland
[2] Lodz Univ Technol, Inst Polymer & Dye Technol, 12-16 Stefanowskiego St, PL-90924 Lodz, Poland
[3] Lodz Univ Technol, Inst Fermentat Technol & Microbiol, 171-173 Wolczanska St, PL-90924 Lodz, Poland
[4] Natl Sugar Co SA, 12 John Paul II Ave, PL-00001 Warsaw, Poland
[5] Univ Alabama Birmingham, Dept Phys, Birmingham, AL 35294 USA
关键词
LACTIC-ACID PRODUCTION; BIOETHANOL PRODUCTION; SELECTIVE OXIDATION; HYDROGEN-PRODUCTION; 2,5-FURANDICARBOXYLIC ACID; BIOGAS PRODUCTION; 5-HYDROXYMETHYLFURFURAL HMF; CATALYTIC DEHYDRATION; CURRENT PERSPECTIVES; SUPPORTED CATALYSTS;
D O I
10.1039/c7ra12782k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This paper presents an overview of alternative uses for products of sugar beet processing, especially sucrose, as chemical raw materials for the production of biodegradable polymers. Traditionally, sucrose has not been considered as a chemical raw material, because of its use in the food industry and high sugar prices. Beet pulp and beetroot leaves have also not been considered as raw materials for chemical production processes until recently. However, current changes in the European sugar market could lead to falling demand and overproduction of sucrose. Increases in the production of white sugar will also increase the production of waste biomass, as a result of the processing of larger quantities of sugar beet. This creates an opportunity for the development of new chemical technologies based on the use of products of sugar beet processing as raw materials. Promising methods for producing functionalized materials include the acidic hydrolysis of sugars (sucrose, biomass polysaccharides), the catalytic dehydration of monosaccharides to HMF followed by catalytic oxidation of HMF to FDCA and polymerization to biodegradable polymers. The technologies reviewed in this article will be of interest both to industry and science.
引用
收藏
页码:3161 / 3177
页数:17
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