Dinuclear Schiff-base copper(II) complexes with various bridging groups

被引：17

作者：

Xian, Dong-Mei ^{[1
]}

You, Zhong-Lu ^{[1
]}

Zhang, Mei ^{[1
]}

Hou, Peng ^{[1
]}

Li, Xiao-Hui ^{[1
]}

机构：

[1] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian 116029, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 18期

基金：

美国国家科学基金会;

关键词：

Schiff base; Copper complex; Dinuclear complex; Crystal structure; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; LIGAND; NICKEL(II);

D O I：

10.1080/00958972.2011.619261

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new centrosymmetric dinuclear copper(II) complexes, [Cu2Cl2(L-1)(2)] (1), [Cu-2(mu(1,)3-NCS)(2) (L-2)(2)] (2), and [Cu-2(mu(1,1)-N-3)(2)(L-3)(2)] (3), where L-1, L-2, and L-3 are the deprotonated forms of the Schiff bases 1-[(2-propylaminoethylimino) methyl] naphthalen-2-ol (HL1), 1-[(3-methylaminopropylimino) methyl] naphthalen-2-ol (HL2), and 2-[(2-isopropylaminoethylimino)methyl] phenol (HL3), respectively, have been prepared and characterized by elemental analysis, IR spectra, and single-crystal X-ray crystallography. Each Cu is coordinated by the three donors of the Schiff bases and by two bridging groups, forming a square-pyramidal geometry.

引用

页码：3265 / 3272

页数：8

共 22 条

[1] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE [J].

ADDISON, AW ;

RAO, TN ;

REEDIJK, J ;

VANRIJN, J ;

VERSCHOOR, GC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07) :1349-1356

[2]

[Anonymous], 2002, SMART CARD INTEGRATI

[3] Dinuclear complexes of MII thiocyanate (M = Ni and Cu) containing a tridentate Schiff-base ligand:: Synthesis, structural diversity and magnetic properties [J].

Banerjee, S ;

Drew, MGB ;

Lu, CZ ;

Tercero, J ;

Diaz, C ;

Ghosh, A .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (12) :2376-2383

[4] Structure and luminescence of a nitrate-bridged heterotrinuclear Cu2-Pr complex with compartmental Schiff base ligand [J].

Banu, Kazi Sabnam ;

Ghosh, Totan ;

Guha, Averi ;

Chattopadhyay, Tanmay ;

Das, Debasis ;

Zangrando, Ennio .

JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (21) :3714-3723

[5] Acetato and formato copper(II) paddle-wheel complexes with nitrogen ligands [J].

Barquin, Montserrat ;

Cocera, Nerea ;

Gonzalez Garmendia, Maria J. ;

Larrinaga, Liher ;

Pinilla, Elena ;

Torres, Maria R. .

JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (13) :2247-2260

[6] Ligand flexibility and dual complexation modes on reaction of 1,2-bis(2′-pyridylethynyl)benzene with copper(I) halides [J].

Bosch, E ;

Barnes, CL .

JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (04) :329-336

[7] Synthesis, crystal structure, electrochemical and magnetic properties of dinuclear complexes with strong electron-drawing groups in the diphenoxo-tetraaza macrocyclic ligand [J].

Chen, Lei ;

Bai, Jun-Lin ;

Zhou, Hong ;

Pan, Zhi-Quan ;

Huang, Qi-Mao ;

Song, You .

JOURNAL OF COORDINATION CHEMISTRY, 2008, 61 (09) :1412-1422

[8] Syntheses, crystal structures, and properties of two macrocyclic dinuclear Ni(II) complexes bearing 2-pyridylmethyl pendant-arms [J].

Cheng, Q. R. ;

Chen, J. Z. ;

Zhou, H. ;

Pan, Z. Q. .

JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (07) :1139-1152

[9] Synthesis, structure, DNA binding, and cleavage activity of two copper(II) complexes [J].

Gao, Chunyan ;

Ma, Xiaofang ;

Lu, Jing ;

Wang, Zhigang ;

Tian, Jinlei ;

Yan, Shiping .

JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (12) :2157-2169

[10] USE OF CONDUCTIVITY MEASUREMENTS IN ORGANIC SOLVENTS FOR CHARACTERISATION OF COORDINATION COMPOUNDS [J].

GEARY, WJ .

COORDINATION CHEMISTRY REVIEWS, 1971, 7 (01) :81-&

← 1 2 3 →