Stereoselective synthesis of highly substituted trans-2,3-dihydrofuran and trans-1,2-cyclopropane derivatives containing sulfonyl groups

被引：38
作者：
Cao, Weiguo [1 ,2 ]
Zhang, Hui [1 ]
Chen, Jie [1 ]
Zhou, Xiaohong [1 ]
Shao, Min [3 ]
McMills, Mark C. [4 ]
机构：
[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
[3] Shanghai Univ, Inst Anal & Res Ctr, Shanghai 200444, Peoples R China
[4] Ohio Univ, Dept Chem & Biochem, Athens, OH 45701 USA
来源：
TETRAHEDRON | 2008年 / 64卷 / 01期
基金：
中国国家自然科学基金; 上海市自然科学基金;
关键词：
D O I：
10.1016/j.tet.2007.10.073
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
trans-2,3-Dihydrofuran derivatives 3 and trans-1,2-cyclopropane derivatives 4 were prepared with high chemoselectivity and moderate overall chemical yield by the reaction of alpha,beta-unsaturated sulfones 1 with arsonium bromides 2 in the presence of potassium carbonate. The structures of products obtained were identified by IR, MS, (1)H NMR, elemental analysis, and X-ray diffraction analysis. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：163 / 167
页数：5
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