Further numerical analyses on the solubility of diazepam in aqueous tert-butanol mixtures

被引：0

作者：

Jouyban, Abolghasem ^{[1
,2
,3
]}

Acree, William E. ^{[4
]}

Martinez, Fleming ^{[5
]}

机构：

[1] Tabriz Univ Med Sci, Pharmaceut Anal Res Ctr, Tabriz, Iran

[2] Tabriz Univ Med Sci, Fac Pharm, Tabriz, Iran

[3] Univ Tehran Med Sci, Digest Dis Res Inst, Tehran, Iran

[4] Univ North Texas, Dept Chem, Denton, TX 76203 USA

[5] Univ Nacl Colombia, Dept Farm, Grp Invest Farmaceuticofisicoquim, Bogota, Colombia

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2021年 / 59卷 / 04期

关键词：

Diazepam; (tert-butanol plus water) mixtures; solubility; Jouyban-Acree model; preferential solvation; PLUS WATER MIXTURES; PREFERENTIAL SOLVATION; PROPYLENE-GLYCOL; SOLVENT MIXTURES; MATHEMATICAL REPRESENTATION; COSOLVENT MIXTURES; TERNARY MIXTURES; LAMOTRIGINE; CLONAZEPAM; BINARY;

D O I：

10.1080/00319104.2020.1743703

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mole fraction equilibrium solubility of diazepam in some {tert-butanol (1) + water (2)} mixtures at several temperatures has been correlated by means of the Jouyban-Acree model and also to evaluate the preferential solvation of this compound by the mixtures components. By using the inverse Kirkwood-Buff integrals method apparently is observed that diazepam is preferentially solvated by water in water-rich and tert-butanol-rich mixtures but preferentially solvated by tert-butanol in mixtures of similar proportions of both solvents.

引用

页码：512 / 522

页数：11

共 38 条

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