Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

被引：57
作者：
Leeland, James W. [1 ]
White, Fraser J. [1 ]
Love, Jason B. [1 ]
机构：
[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 19期
基金：
英国工程与自然科学研究理事会;
关键词：
HYDROGEN-BONDS; INTERMOLECULAR FORCES; EXPANDED PORPHYRIN; METAL-CATIONS; DIELS-ALDER; COMPLEXES; CAPSULES; HOST; CATALYSIS; FUNCTIONALIZATION;
D O I：
10.1021/ja201630b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrolysis of a Pacman-shaped binuclear magnesium complex of a polypyrrolic Schiff base macrocycle results in the formation of a new magnesium hydroxide cubane that is encapsulated by the macrocyclic framework through both coordinative and hydrogen-bonding interactions.
引用
收藏
页码：7320 / 7323
页数：4
相关论文
共 66 条
[41]   A macrocyclic approach to transition metal and uranyl Pacman complexes [J].
Love, Jason B. .
CHEMICAL COMMUNICATIONS, 2009, (22) :3154-3165
[42]   A chiral spherical molecular assembly held together by 60 hydrogen bonds [J].
MacGillivray, LR ;
Atwood, JL .
NATURE, 1997, 389 (6650) :469-472
[43]   An Unlockable-Relockable Iron Cage by Subcomponent Self-Assembly [J].
Mal, Prasenjit ;
Schultz, David ;
Beyeh, Kodiah ;
Rissanen, Kari ;
Nitschke, Jonathan R. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (43) :8297-8301
[44]   White Phosphorus Is Air-Stable Within a Self-Assembled Tetrahedral Capsule [J].
Mal, Prasenjit ;
Breiner, Boris ;
Rissanen, Kari ;
Nitschke, Jonathan R. .
SCIENCE, 2009, 324 (5935) :1697-1699
[45]  
Meeuwissen J, 2010, NAT CHEM, V2, P615, DOI [10.1038/nchem.744, 10.1038/NCHEM.744]
[46]   AUTOENCAPSULATION THROUGH INTERMOLECULAR FORCES - A SYNTHETIC SELF-ASSEMBLING SPHERICAL COMPLEX [J].
MEISSNER, RS ;
REBEK, J ;
DEMENDOZA, J .
SCIENCE, 1995, 270 (5241) :1485-1488
[47]  
Merlau ML, 2001, ANGEW CHEM INT EDIT, V40, P4239, DOI 10.1002/1521-3773(20011119)40:22<4239::AID-ANIE4239>3.0.CO
[48]  
2-E
[49]   Controlling photoreactions with restricted spaces and weak intermolecular forces: Exquisite selectivity during oxidation of olefins by singlet oxygen [J].
Natarajan, Arunkumar ;
Kaanumalle, Lakshmi S. ;
Jockusch, Steffen ;
Gibb, Corinne L. D. ;
Gibb, Bruce C. ;
Turro, Nicholas J. ;
Ramamurthy, V. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (14) :4132-+
[50]   Acid catalysis in basic solution: A supramolecular host promotes orthoformate hydrolysis [J].
Pluth, Michael D. ;
Bergman, Robert G. ;
Raymond, Kenneth N. .
SCIENCE, 2007, 316 (5821) :85-88
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