Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

被引：57

作者：

Leeland, James W. ^{[1
]}

White, Fraser J. ^{[1
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 19期

基金：

英国工程与自然科学研究理事会;

关键词：

HYDROGEN-BONDS; INTERMOLECULAR FORCES; EXPANDED PORPHYRIN; METAL-CATIONS; DIELS-ALDER; COMPLEXES; CAPSULES; HOST; CATALYSIS; FUNCTIONALIZATION;

D O I：

10.1021/ja201630b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrolysis of a Pacman-shaped binuclear magnesium complex of a polypyrrolic Schiff base macrocycle results in the formation of a new magnesium hydroxide cubane that is encapsulated by the macrocyclic framework through both coordinative and hydrogen-bonding interactions.

引用

页码：7320 / 7323

页数：4

共 66 条

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