Encapsulation of a Magnesium Hydroxide Cubane by a Bowl-Shaped Polypyrrolic Schiff Base Macrocycle

被引：57
作者：
Leeland, James W. [1 ]
White, Fraser J. [1 ]
Love, Jason B. [1 ]
机构：
[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 19期
基金：
英国工程与自然科学研究理事会;
关键词：
HYDROGEN-BONDS; INTERMOLECULAR FORCES; EXPANDED PORPHYRIN; METAL-CATIONS; DIELS-ALDER; COMPLEXES; CAPSULES; HOST; CATALYSIS; FUNCTIONALIZATION;
D O I：
10.1021/ja201630b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrolysis of a Pacman-shaped binuclear magnesium complex of a polypyrrolic Schiff base macrocycle results in the formation of a new magnesium hydroxide cubane that is encapsulated by the macrocyclic framework through both coordinative and hydrogen-bonding interactions.
引用
收藏
页码：7320 / 7323
页数：4
相关论文
共 66 条
[1]   Highly symmetric networks derived from cubane-related octametallic complexes of a new oxyanion of carbon, C4O74-, each molecule attached to eight neighbors by 24 equivalent hydrogen bonds [J].
Abrahams, BF ;
Hudson, TA ;
Robson, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (28) :8624-8625
[2]   Adaptations of guest and host in expanded self-assembled capsules [J].
Ajami, Dariush ;
Rebek, Julius, Jr. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (41) :16000-16003
[3]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[4]   Reduction and selective oxo group silylation of the uranyl dication [J].
Arnold, Polly L. ;
Patel, Dipti ;
Wilson, Claire ;
Love, Jason B. .
NATURE, 2008, 451 (7176) :315-U3
[5]   Selective oxo functionalization of the uranyl ion with 3d metal cations [J].
Arnold, Polly L. ;
Patel, Dipti ;
Blake, Alexander J. ;
Wilson, Claire ;
Love, Jason B. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (30) :9610-9611
[6]  
Arnold PL, 2010, NAT CHEM, V2, P1056, DOI [10.1038/nchem.904, 10.1038/NCHEM.904]
[7]   Tailoring dicobalt Pacman complexes of Schiff-base calixpyrroles towards dioxygen reduction catalysis [J].
Askarizadeh, Elham ;
Yaghoob, Sahar Bani ;
Boghaei, Davar M. ;
Slawin, Alexandra M. Z. ;
Love, Jason B. .
CHEMICAL COMMUNICATIONS, 2010, 46 (05) :710-712
[8]   Photosynthetic generation of oxygen [J].
Barber, James .
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES, 2008, 363 (1504) :2665-2674
[9]   ENCAPSULATION OF METHANE AND OTHER SMALL MOLECULES IN A SELF-ASSEMBLING SUPERSTRUCTURE [J].
BRANDA, N ;
WYLER, R ;
REBEK, J .
SCIENCE, 1994, 263 (5151) :1267-1268
[10]   Supermolecules by design [J].
Caulder, DL ;
Raymond, KN .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :975-982
1234567