Green Bipropellants: Hydrogen-Rich Ionic Liquids that Are Hypergolic with Hydrogen Peroxide

被引：134
作者：
Schneider, Stefan [1 ]
Hawkins, Tom [1 ]
Ahmed, Yonis [1 ]
Rosander, Michael [1 ]
Hudgens, Leslie [1 ]
Mills, Jeff [1 ]
机构：
[1] USAF, Res Lab, Edwards AFB, CA 93524 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 26期
关键词：
hydrogen peroxide; hydrogen-rich fuels; hypergolicity; ionic liquids; propellants; SODIUM-BOROHYDRIDE; IODIDES; FUELS;
D O I：
10.1002/anie.201101752
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Lift-off: The low vapor toxicity of ionic liquids (ILs) make them attractive replacements for hydrazine in rocket fuel. However, ILs will fail to fulfill their revolutionary promise unless toxic oxidizers such as HNO 3 or N2O4 can be replaced with safer alternatives such as H2O2. The ILs presented here are hypergolic with H2O2 (see picture) and are hydrogen-rich, thus helping to boost performance. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5886 / 5888
页数：3
相关论文
共 50 条
  • [21] Real-Time Monitoring of Hydrogen Peroxide Consumption in an Oxidation Reaction in Molecular Solvent and Ionic Liquids by a Hydrogen Peroxide Electrochemical Sensor
    Sordi, Daniela
    Arduini, Fabiana
    Conte, Valeria
    Moscone, Danila
    Palleschi, Giuseppe
    CHEMSUSCHEM, 2011, 4 (06) : 792 - 796
  • [22] An experimental study on the hypergolic ignition of hydrogen peroxide and ethanolamine
    Ak, M. A.
    Ulas, A.
    Sumer, B.
    Yazici, B.
    Yildirim, C.
    Gonc, L. O.
    Orhan, F. E.
    FUEL, 2011, 90 (01) : 395 - 398
  • [23] Hypergolic propellants based on hydrogen peroxide and organic compounds: historical aspect and current state
    Guseinov, Sh. L.
    Fedorov, S. G.
    Kosykh, V. A.
    Storozhenko, P. A.
    RUSSIAN CHEMICAL BULLETIN, 2018, 67 (11) : 1943 - 1954
  • [24] Hypergolic ignition of hydrogen peroxide with various solid fuels
    Castaneda, David A.
    Natan, Benveniste
    FUEL, 2022, 316
  • [25] Green bipropellant development-A study on the hypergolicity of imidazole thiocyanate ionic liquids with hydrogen peroxide in an automated drop test setup
    Lauck, Felix
    Balkenhohl, Jakob
    Negri, Michele
    Freudenmann, Dominic
    Schlechtriem, Stefan
    COMBUSTION AND FLAME, 2021, 226 : 87 - 97
  • [26] Epoxidation of styrene to styrene oxide using carbon dioxide and hydrogen peroxide in ionic liquids
    Song, Jinliang
    Zhang, Zhaofu
    Jiang, Tao
    Hu, Suqin
    Li, Wenjing
    Xie, Ye
    Han, Buxing
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 279 (02) : 235 - 238
  • [27] The Impact of Cation Structures on Hypergolicity of Thiocyanate Ionic Liquids with Hydrogen Peroxide
    Ricker, Sophie C.
    Freudenmann, Dominic
    Schlechtriem, Stefan
    ENERGY & FUELS, 2021, 35 (19) : 16128 - 16133
  • [28] Trialkylsulfonium Thiocyanate Ionic Liquids: Investigation on Temperature-Dependent Ignition Behavior of Green Hypergolic Propellants
    Stoelzle, Sophie C.
    Kruse, Lennart
    Freudenmann, Dominic
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2024, 49 (12)
  • [29] Experimental investigation of the hydrogen peroxide - solid hydrocarbon hypergolic ignition
    Castaneda, David A.
    Natan, Benveniste
    ACTA ASTRONAUTICA, 2019, 158 : 286 - 295
  • [30] Monoethanolamine-Based Fuels Hypergolic with Rocket-Grade Hydrogen Peroxide
    Caffiero, Luca
    Carlotti, Stefania
    Maggi, Filippo
    AEROSPACE, 2024, 11 (04)
12345