Optical nonlinearity, limiting and switching characteristics of novel ruthenium metal-organic complex

被引:28
作者
Manjunatha, K. B. [1 ]
Rajarao, Ravindra [2 ]
Umesh, G. [3 ]
Bhat, B. Ramachandra [4 ]
Poornesh, P. [5 ]
机构
[1] NMAM Inst Technol, Dept Phys, Nitte 574110, India
[2] Univ New South Wales, Sch Mat Sci & Engn, Ctr Sustainable Mat Res & Technol, Sydney, NSW 2052, Australia
[3] Natl Inst Technol Karnataka, Dept Phys, Optoelect Lab, Mangalore 575025, India
[4] Natl Inst Technol Karnataka, Dept Chem, Catalysis & Mat Lab, Mangalore 575025, India
[5] Manipal Univ, Manipal Inst Technol, Dept Phys, Nonlinear Opt Res Lab, Manipal 576104, Karnataka, India
关键词
Nonlinear optics; Z-scan; DFWM; Optical limiting; Z-SCAN; THIN-FILMS; POLYMER;
D O I
10.1016/j.optmat.2017.06.051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report the nonlinear optical properties of Ruthenium metal complex a promising organic material for use in scientific and technological applications. The thin films of newly synthesized ruthenium metal organic complex were fabricated using spin coating technique. Z-scan and degenerate four wave mixing (DFWM) techniques used to extract the third-order nonlinear optical (NLO) parameters. The data reveals the investigated material exhibited relatively large NLO properties. The pump probe experiments shows that the switch-on and off times of the material were in the order of ps at different pump intensities and the energy dependent transmission studies reveal good limiting property of the material in nanosecond regime. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:513 / 517
页数:5
相关论文
共 35 条
[1]   Synthesis and spectroscopic characterization of [CoIII(salophen)(amine)2]ClO4 (amine = morpholine, pyrrolidine, and piperidine) complexes.: The crystal structures of [CoIII(salophen)(morpholine)2]ClO4 and [CIII(salophen)(pyrrolidine)2]ClO4 [J].
Amirnasr, M ;
Schenk, KJ ;
Gorji, A ;
Vafazadeh, R .
POLYHEDRON, 2001, 20 (7-8) :695-702
[2]   Syntheses, characterization and third order non-linear optical properties of the ruthenium(II) complexes containing 2-phenylimidazo[4,5-f][1,10]phenanthroline derivatives [J].
Chao, H ;
Li, RH ;
Yi, BH ;
Li, H ;
Feng, XL ;
Cai, JW ;
Zhou, JY ;
Ji, LN .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (21) :3711-3717
[3]   Influence of the central metal atom on the nonlinear optical properties of MPcs solutions and thin films [J].
Derkowska, B. ;
Wojdyla, M. ;
Czaplicki, R. ;
Bala, W. ;
Sahraoui, B. .
OPTICS COMMUNICATIONS, 2007, 274 (01) :206-212
[4]   Second-order nonlinear optical properties of transition metal complexes [J].
Di Bella, S .
CHEMICAL SOCIETY REVIEWS, 2001, 30 (06) :355-366
[5]   Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation [J].
Gao, Beibei ;
Mazur, Leszek M. ;
Morshedi, Mahbod ;
Barlow, Adam ;
Wang, Huan ;
Quintana, Cristobal ;
Zhang, Chi ;
Samoc, Marek ;
Cifuentes, Marie P. ;
Humphrey, Mark G. .
CHEMICAL COMMUNICATIONS, 2016, 52 (53) :8301-8304
[6]   Zinc Induced a Dramatic Enhancement of the Nonlinear Optical Properties of an Azo-Based Iminopyridine Ligand [J].
Guezguez, Imen ;
Ayadi, Awatef ;
Ordon, Karolina ;
Iliopoulos, Konstantinos ;
Branzea, Diana G. ;
Migalska-Zalas, Anna ;
Makowska-Janusik, Malgorzata ;
El-Ghayoury, Abdelkrim ;
Sahraoui, Bouchta .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (14) :7545-7553
[7]   Investigation of optical nonlinearities in Pd(po)2 by Z-scan technique [J].
Guo, SL ;
Xu, L ;
Wang, HT ;
You, XZ ;
Ming, NB .
OPTIK, 2003, 114 (02) :58-62
[8]  
Hales J.M., 2008, INTRO ORGANIC ELECT
[9]   Third-order optical non-linearity in Zn(II) complexes of 5,10,15,20-tetraarylethynyl-substituted porphyrins [J].
Henari, FZ ;
Blau, WJ ;
Milgrom, LR ;
Yahioglu, G ;
Phillips, D ;
Lacey, JA .
CHEMICAL PHYSICS LETTERS, 1997, 267 (3-4) :229-233
[10]   Optical switching in organometallic phthalocyanine [J].
Henari, FZ .
JOURNAL OF OPTICS A-PURE AND APPLIED OPTICS, 2001, 3 (03) :188-190