Synthesis of calix[4]resorcinarenes, containing phosphoryl fragments at the lower rim of the molecule

被引：11

作者：

Burilov, A. R. ^{[1
]}

Knyazeva, I. R. ^{[1
]}

Sadykova, Yu. M. ^{[1
]}

Pudovik, M. A. ^{[1
]}

Habicher, W. D. ^{[2
]}

Baier, I. ^{[2
]}

Konovalova, A. I. ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

[2] Tech Univ Dresden, Inst Organ Chem, D-01062 Dresden, Germany

来源：

RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

acetals; vinylphosphonic acids; resorcinols; calix[4] resorcinarenes; organophosphorus compounds;

D O I：

10.1007/s11172-007-0173-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of resorcinol with phosphorylated acetals or ethoxyvinylphosphonic acid esters in acidic media leads to calix[4] resorcinarenes, containing dialkoxyphosphoryl fragments at the lower rim of the molecule. When the alkyl substituent in alkoxy groups at phosphorus atom is not very long, a partial hydrolysis of the initially formed products takes place to give calixarenes with alkoxyhydroxyphosphoryl fragments.

引用

页码：1144 / 1148

页数：5

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