Synthesis of calix[4]resorcinarenes, containing phosphoryl fragments at the lower rim of the molecule

被引:11
作者
Burilov, A. R. [1 ]
Knyazeva, I. R. [1 ]
Sadykova, Yu. M. [1 ]
Pudovik, M. A. [1 ]
Habicher, W. D. [2 ]
Baier, I. [2 ]
Konovalova, A. I. [1 ]
机构
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
[2] Tech Univ Dresden, Inst Organ Chem, D-01062 Dresden, Germany
基金
俄罗斯基础研究基金会;
关键词
acetals; vinylphosphonic acids; resorcinols; calix[4] resorcinarenes; organophosphorus compounds;
D O I
10.1007/s11172-007-0173-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of resorcinol with phosphorylated acetals or ethoxyvinylphosphonic acid esters in acidic media leads to calix[4] resorcinarenes, containing dialkoxyphosphoryl fragments at the lower rim of the molecule. When the alkyl substituent in alkoxy groups at phosphorus atom is not very long, a partial hydrolysis of the initially formed products takes place to give calixarenes with alkoxyhydroxyphosphoryl fragments.
引用
收藏
页码:1144 / 1148
页数:5
相关论文
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