Alloyed (ZnS)x(Cu2SnS3)1-x and (CuInS2)x(Cu2SnS3)1-x nanocrystals with arbitrary composition and broad tunable band gaps

被引：104

作者：

Liu, Qinghui ^{[1
,2
]}

Zhao, Zechen ^{[1
]}

Lin, Yuhan ^{[1
]}

Guo, Peng ^{[1
]}

Li, Shenjie ^{[1
]}

Pan, Daocheng ^{[1
]}

Ji, Xiangling ^{[2
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 03期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

CU2ZNSNS4; NANOCRYSTALS; SOLAR-CELLS; CU2SNS3; SYSTEM; ROUTE;

D O I：

10.1039/c0cc03560b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cu2SnS3 nanocrystals with metastable zincblende and wurtzite structures have been successfully synthesized for the first time. Alloyed (ZnS)(x)(Cu2SnS3)(1-x) and (CuInS2)(x)(Cu2SnS3)(1-x) nanocrystals with arbitrary composition (0 <= x <= 1) and ultra-broad tunable band gaps (3.63 to 0.94 eV) were obtained.

引用

页码：964 / 966

页数：3

共 19 条

[1]

[Anonymous], J PHYS D

[2] Phase-Selective Synthesis of CuInS2 Nanocrystals [J].

Batabyal, Sudip K. ;

Tian, Lu ;

Venkatram, N. ;

Ji, Wei ;

Vittal, Jagadese J. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (33) :15037-15042

[3] Preparation and characterization of ternary Cu-Sn-E (E = S, Se) semiconductor nanocrystallites via a solvothermal element reaction route [J].

Chen, XY ;

Wang, X ;

An, CH ;

Liu, JW ;

Qian, YT .

JOURNAL OF CRYSTAL GROWTH, 2003, 256 (3-4) :368-376

[4] One-pot synthesis of copper-indium sulfide nanocrystal heterostructures with acorn, bottle, and larva shapes [J].

Choi, SH ;

Kim, EG ;

Hyeon, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (08) :2520-2521

[5] Band-gap tunable (Cu2Sn)x/3Zn1-xS nanoparticles for solar cells [J].

Dai, Pengcheng ;

Shen, Xiangna ;

Lin, Zhaojun ;

Feng, Zhenyu ;

Xu, Hui ;

Zhan, Jinhua .

CHEMICAL COMMUNICATIONS, 2010, 46 (31) :5749-5751

[6] Phase relations and optical properties of semiconducting ternary sulfides in the system Cu-Sn-S [J].

Fiechter, S ;

Martinez, M ;

Schmidt, G ;

Henrion, W ;

Tomm, Y .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (9-10) :1859-1862

[7] Synthesis of Cu2ZnSnS4 Nanocrystal Ink and Its Use for Solar Cells [J].

Guo, Qijie ;

Hillhouse, Hugh W. ;

Agrawal, Rakesh .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (33) :11672-+

[8] Development of CZTS-based thin film solar cells [J].

Katagiri, Hironori ;

Jimbo, Kazuo ;

Maw, Win Shwe ;

Oishi, Koichiro ;

Yamazaki, Makoto ;

Araki, Hideaki ;

Takeuchi, Akiko .

THIN SOLID FILMS, 2009, 517 (07) :2455-2460

[9] Synthesis of CuInS2 nanocrystals and their structural transformation triggered by ligand exchange [J].

Katsuhiro, Nose ;

Yuki, Soma ;

Takahisa, Omata ;

Shinya, Otsuka-Yao-Matsuo .

CHINESE SCIENCE BULLETIN, 2009, 54 (21) :4005-4008

[10] PHOTOVOLTAIC CHARACTERISTICS OF THIN-FILMS OF CU2SNS3 [J].

KUKU, TA ;

FAKOLUJO, OA .

SOLAR ENERGY MATERIALS, 1987, 16 (1-3) :199-204

← 1 2 →