Dielectric and conductivity properties of flux grown Ce doped NBT-BT single crystals

被引:9
作者
Sundari, S. Shanmuga [1 ,2 ]
Kumar, Binay [3 ]
Dhanasekaran, R. [1 ]
机构
[1] Anna Univ, Crystal Growth Ctr, Chennai 600025, Tamil Nadu, India
[2] PSGR Krishnammal Coll Women, Coimbatore 641004, Tamil Nadu, India
[3] Univ Delhi, Dept Phys & Astrophys, Crystal Lab, Delhi 110007, India
关键词
Relaxor ferroelectrics; Crystal growth; Dielectric relaxation; X-ray diffraction; Activation energy; MORPHOTROPIC-PHASE-BOUNDARY; ELECTRICAL-PROPERTIES; TRANSITIONS; BEHAVIOR; SYSTEM;
D O I
10.1016/j.physb.2019.411978
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
To study the effect of Ce in the NBT-BT lattice, 0.4 wt% of CeO2 was added to the 0.94(Na0.5Bi0.5TiO3)-0.06BaTiO(3), in its morphotmpic phase boundary (MPB) composition, and the single crystals were grown by the flux method using Bi2O3 as a flux. The structural studies were carried by the XRD and Raman analyses. The dielectric constants were measured from room temperature to 400 degrees C for various frequencies in the range of 20 Hz-2 MHz. The anti-ferroelectric temperature region is increasing due to the addition of Ce in the NBT-BT. The maximum value of dielectric loss is also found to decrease from 0.4% to 0.1% due to the Ce addition. The conductivity and impedance analyses were carried out to study the relaxation process of Ce-NBT-BT single crystals.
引用
收藏
页数:7
相关论文
共 28 条
[1]   Enhancement of ferroelectric properties of Na1/2Bi1/2TiO3-BaTiO3 single crystals by Ce dopings [J].
Babu, J. Bubesh ;
He, Ming ;
Zhang, D. F. ;
Chen, X. L. ;
Dhanasekaran, R. .
APPLIED PHYSICS LETTERS, 2007, 90 (10)
[2]   Inhomogeneity issues in the growth of Na1/2Bi1/2TiO3-BaTiO3 single crystals [J].
Babu, J. Bubesh ;
Madeswaran, G. ;
He, Ming ;
Zhang, D. F. ;
Chen, X. L. ;
Dhanasekaran, R. .
JOURNAL OF CRYSTAL GROWTH, 2008, 310 (02) :467-472
[3]   Effect of CeO2 addition on structure and electrical properties of (Na0.5Bi0.5)0.93Ba0.07TiO3 ceramics prepared by citric method [J].
Chen, Min ;
Xu, Qing ;
Kim, Bok Hee ;
Ahn, Byeong Kuk ;
Chen, Wen .
MATERIALS RESEARCH BULLETIN, 2008, 43 (06) :1420-1430
[4]   Investigation of glassy behavior of lead magnesium niobate relaxors [J].
Cheng, ZY ;
Zhang, LY ;
Yao, X .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (11) :8615-8619
[5]  
CROSS LE, 1987, FERROELECTRICS, V76, P241, DOI [10.1080/00150198708016945, 10.2109/jcersj.99.829]
[6]   Relationship between local structure and phase transitions of a disordered solid solution [J].
Grinberg, I ;
Cooper, VR ;
Rappe, AM .
NATURE, 2002, 419 (6910) :909-911
[7]   Preface to Special Topic: Piezoresponse Force Microscopy and Nanoscale Phenomena in Polar Materials [J].
Kalinin, Sergei V. ;
Ye, Zuo-Guang ;
Kholkin, Andrei L. .
JOURNAL OF APPLIED PHYSICS, 2012, 112 (05)
[8]   An x-ray diffraction and Raman spectroscopy investigation of A-site substituted perovskite compounds:: the (Na1-xKx)0.5Bi0.5TiO3 (0≤x≤1) solid solution [J].
Kreisel, J ;
Glazer, AM ;
Jones, G ;
Thomas, PA ;
Abello, L ;
Lucazeau, G .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2000, 12 (14) :3267-3280
[9]   Phase transitions and dielectric properties in A-site ion substituted (Na1/2Bi1/2)TiO3 ceramics (A=Pb and Sr) [J].
Lee, JK ;
Hong, KS ;
Kim, CK ;
Park, SE .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (07) :4538-4542
[10]   Crystal Structure, dielectric and ferroelectric properties of (Bi0.5Na0.5)TiO3-(Ba,Sr)TiO3 lead-free piezoelectric ceramics [J].
Lee, Wei-Chih ;
Huang, Chi-Yuen ;
Tsao, Liang-Kuo ;
Wu, Yu-Chun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 492 (1-2) :307-312