Long-range magnetic ordering in a TbIII-MoV cyanido-bridged quasi-one-dimensional complex

被引：107
作者：
Prins, Ferry
Pasca, Edoardo
de Jongh, L. Jos
Kooijman, Huub
Spek, Anthony L.
Tanase, Stefania
机构：
[1] Leiden Univ, Kamerlingh Onnes Lab, Leiden Inst Phys, NL-2300 RA Leiden, Netherlands
[2] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[3] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 32期
关键词：
heterometallic complexes; lanthanicles; magnetic properties; molybdenum; N; O ligands;
D O I：
10.1002/anie.200701847
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) One-dimensional polymer [Tb(pzam)3(H 2O)Mo(CN)8]·H2O (see picture, pzam = pyrazine-2-carboxamide; C black, Mo yellow, N blue, O red, Tb green) has been synthesized and characterized. Its magnetic susceptibility data indicate substantial ferromagnetic superexchange between TbIII and Mo V via the cyanido bridge, and the occurrence of long-range magnetic ordering between chains at Tc ≈ 1 K. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：6081 / 6084
页数：4
相关论文
共 27 条
[1]  
Abragam A., 2012, ELECT PARAMAGNETIC R
[2]   EPR STUDIES OF PHOTOCHROMIC CAF2 [J].
ANDERSON, CH ;
SABISKY, ES .
PHYSICAL REVIEW B, 1971, 3 (02) :527-&
[3]   Organic and molecular magnets [J].
Blundell, SJ ;
Pratt, FL .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (24) :R771-R828
[4]  
Carlin R.L., 1997, MAGNETOCHEMISTRY
[5]  
de Jongh LJ, 2001, ADV PHYS, V50, P947, DOI 10.1080/00018730110101412
[6]   HIGH-TEMPERATURE MOLECULAR MAGNETS BASED ON CYANOVANADATE BUILDING-BLOCKS - SPONTANEOUS MAGNETIZATION AT 230-K [J].
ENTLEY, WR ;
GIROLAMI, GS .
SCIENCE, 1995, 268 (5209) :397-400
[7]  
Evangelisti M., 2003, PHYS REV B, V68, P2534
[8]  
Herrera J. M., 2004, ANGEW CHEM, V116, P5584
[9]   Reversible photoinduced magnetic properties in the heptanuclear complex [MoIV(CN)2(CN-CuL)6]8+:: A photomagnetic high-spin molecule [J].
Herrera, JM ;
Marvaud, V ;
Verdaguer, M ;
Marrot, J ;
Kalisz, M ;
Mathonière, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (41) :5468-5471
[10]   Cyano-bridged gadolinium(III)-tungstate(V) bimetallic assembly with a one-dimensional chain structure [J].
Ikeda, S ;
Hozumi, T ;
Hashimoto, K ;
Ohkoshi, S .
DALTON TRANSACTIONS, 2005, (12) :2120-2123
123