Long-range magnetic ordering in a TbIII-MoV cyanido-bridged quasi-one-dimensional complex

被引：107
作者：
Prins, Ferry
Pasca, Edoardo
de Jongh, L. Jos
Kooijman, Huub
Spek, Anthony L.
Tanase, Stefania
机构：
[1] Leiden Univ, Kamerlingh Onnes Lab, Leiden Inst Phys, NL-2300 RA Leiden, Netherlands
[2] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[3] Univ Utrecht, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 32期
关键词：
heterometallic complexes; lanthanicles; magnetic properties; molybdenum; N; O ligands;
D O I：
10.1002/anie.200701847
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) One-dimensional polymer [Tb(pzam)3(H 2O)Mo(CN)8]·H2O (see picture, pzam = pyrazine-2-carboxamide; C black, Mo yellow, N blue, O red, Tb green) has been synthesized and characterized. Its magnetic susceptibility data indicate substantial ferromagnetic superexchange between TbIII and Mo V via the cyanido bridge, and the occurrence of long-range magnetic ordering between chains at Tc ≈ 1 K. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6081 / 6084
页数：4
相关论文
共 27 条
  • [1] Abragam A., 2012, ELECT PARAMAGNETIC R
  • [2] EPR STUDIES OF PHOTOCHROMIC CAF2
    ANDERSON, CH
    SABISKY, ES
    [J]. PHYSICAL REVIEW B, 1971, 3 (02): : 527 - &
  • [3] Organic and molecular magnets
    Blundell, SJ
    Pratt, FL
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (24) : R771 - R828
  • [4] Carlin R.L., 1997, MAGNETOCHEMISTRY
  • [5] de Jongh LJ, 2001, ADV PHYS, V50, P947, DOI 10.1080/00018730110101412
  • [6] HIGH-TEMPERATURE MOLECULAR MAGNETS BASED ON CYANOVANADATE BUILDING-BLOCKS - SPONTANEOUS MAGNETIZATION AT 230-K
    ENTLEY, WR
    GIROLAMI, GS
    [J]. SCIENCE, 1995, 268 (5209) : 397 - 400
  • [7] Evangelisti M., 2003, PHYS REV B, V68, P2534
  • [8] Herrera J. M., 2004, ANGEW CHEM, V116, P5584
  • [9] Reversible photoinduced magnetic properties in the heptanuclear complex [MoIV(CN)2(CN-CuL)6]8+:: A photomagnetic high-spin molecule
    Herrera, JM
    Marvaud, V
    Verdaguer, M
    Marrot, J
    Kalisz, M
    Mathonière, C
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (41) : 5468 - 5471
  • [10] Cyano-bridged gadolinium(III)-tungstate(V) bimetallic assembly with a one-dimensional chain structure
    Ikeda, S
    Hozumi, T
    Hashimoto, K
    Ohkoshi, S
    [J]. DALTON TRANSACTIONS, 2005, (12) : 2120 - 2123
123