Blue fluorescence from pyridinyl coumarincarboxymides structure having high quantum yield in solution

被引:2
作者
Zhou, Zichun [1 ]
Tang, Xue [1 ]
Cui, Yanhong [1 ]
Xue, Shuai [1 ]
Yu, Zihua [1 ]
Li, Yujin [1 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China
关键词
Pyridinecarboxamide; Coumarin; Blue fluorescence; High quantum yield; TD-DFT calculations; SOLID-STATE FLUORESCENCE; COUMARIN DERIVATIVES; DYES; DESIGN;
D O I
10.1016/j.molstruc.2021.131229
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Small molecules having fluorescence quantum yields are required to promote biological and organic material applications. In this work, we introduced a series of pyridinyl coumarincarboxymides derivatives, namely 4-XP. These compounds exhibited intense blue fluorescence with high fluorescence quantum yield. By spectral measurement and analysis, it is identified that these pyridine-coumarin conjugates displayed high fluorescence quantum yields (Phi(F) = 0.77-0.82) blue fluorescence at about 455 nm in nonpolar solvents. Additionally, the solvent effect and fluorescence properties were verified and explained by DFT and TD-DFT calculations. (C) 2021 Published by Elsevier B.V.
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页数:8
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