Synthesis and structure of a triptycene-based nanosized molecular cage

被引：106
|
作者：
Zhang, Chun [1 ]
Chen, Chuan-Feng [1 ]
机构：
[1] Chinese Acad Sci, Ctr Chem Biol, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100080, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 24期
关键词：
D O I：
10.1021/jo7017526
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[Graphics] A triptycene-based nanosized molecular cage was designed and efficiently synthesized by Eglington-Glaser coupling reaction, and its structure was determined by NMR, MS spectrometry and X-ray analysis. Moreover, it was found that the cage molecules could pack into a microporous structure in the solid state and 1,3,5-trimethylbenzene molecules were located in the channels.
引用
收藏
页码：9339 / 9341
页数：3
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