Visible Light-Induced Aerobic Oxidative Dehydrogenation of C-N/C-O to C=N/C=O Bonds Using Metal-Free Photocatalysts: Recent Developments

被引：15
作者：
Torregrosa-Chinillach, Alejandro [1 ]
Chinchilla, Rafael [1 ]
机构：
[1] Univ Alicante, Inst Organ Synth ISO, Fac Sci, Dept Organ Chem, Apdo 99, Alicante 03080, Spain
来源：
MOLECULES | 2022年 / 27卷 / 02期
关键词：
oxidative dehydrogenation; photocatalysis; metal-free; C-N bond; C-O bond; GRAPHITIC CARBON NITRIDE; POROUS ORGANIC FRAMEWORKS; GRAPHENE QUANTUM DOTS; SELECTIVE OXIDATION; PHOTOREDOX CATALYSIS; MOLECULAR-OXYGEN; H BONDS; EOSIN Y; SYNTHETIC APPLICATIONS; AROMATIC ALCOHOLS;
D O I：
10.3390/molecules27020497
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Performing synthetic transformation using visible light as energy source, in the presence of a photocatalyst as a promoter, is currently of high interest, and oxidation reactions carried out under these conditions using oxygen as the final oxidant are particularly convenient from an environmental point of view. This review summarizes the recent developments achieved in the oxidative dehydrogenation of C-N and C-O bonds, leading to C=N and C=O bonds, respectively, using air or pure oxygen as oxidant and metal-free homogeneous or recyclable heterogeneous photocatalysts under visible light irradiation.
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页数：49
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