Carbon monoxide adsorption on low-silica zeolites-from single to dual and to multiple cation sites

被引：43
作者：
Arean, C. Otero
Delgado, M. Rodriguez
Bauca, C. Lopez
Vrbka, L.
Nachtigall, P. [1 ]
机构：
[1] Univ Balearic Isl, Dept Quim, E-07122 Palma de Mallorca, Spain
[2] Acad Sci Czech Republ, Inst Organ Chem & Biochem, Ctr Biomed & Complex Mol Syst, Prague 16610 6, Czech Republic
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2007年 / 9卷 / 33期
关键词：
D O I：
10.1039/b709073k
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Infrared spectra of CO adsorbed on the Al-rich Na-A zeolite were analysed by using a combined theoretical and experimental approach, showing that such spectra cannot be interpreted by assigning each IR band to CO interacting with a specific type of single cation site. This concept, which usually works well for high-silica zeolites, should not be uncritically extended to Al-rich zeolites that are crowded with cations in configurations which lead to preferential formation of CO adsorption complexes involving more than one cation site.
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收藏
页码：4657 / 4661
页数：5
相关论文
共 16 条
  • [1] Thermodynamics of reversible gas adsorption on alkali-metal exchanged zeolites -: the interplay of infrared spectroscopy and theoretical calculations
    Arean, C. Otero
    Nachtigallova, D.
    Nachtigall, P.
    Garrone, E.
    Delgado, M. Rodriguez
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (12) : 1421 - 1436
  • [2] Areán CO, 2001, EUR J INORG CHEM, P1739
  • [3] IMPROVED TETRAHEDRON METHOD FOR BRILLOUIN-ZONE INTEGRATIONS
    BLOCHL, PE
    JEPSEN, O
    ANDERSEN, OK
    [J]. PHYSICAL REVIEW B, 1994, 49 (23): : 16223 - 16233
  • [4] Calculations of site-specific CO stretching frequencies for copper carbonyls with the "near spectroscopic accuracy":: CO interaction with Cu+/MFI
    Bludsky, O
    Silhan, M
    Nachtigallová, D
    Nachtigall, P
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (48) : 10381 - 10388
  • [5] Vibrational spectroscopy of H2, N2, CO and NO adsorbed on H, Li, Na, K-exchanged ferrierite
    Bordiga, S
    Palomino, GT
    Pazè, C
    Zecchina, A
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 34 (01) : 67 - 80
  • [6] Single and dual cation sites in zeolites:: Theoretical calculations and FTIR spectroscopic studies on CO adsorption on K-FER
    Garrone, E.
    Bulanek, R.
    Frolich, K.
    Otero Arean, C.
    Rodriguez Delgado, M.
    Turnes Palomino, G.
    Nachtigallova, D.
    Nachtigall, P.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (45) : 22542 - 22550
  • [7] Variable temperature infrared spectroscopy:: A convenient tool for studying the thermodynamics of weak solid-gas interactions
    Garrone, E
    Areán, CO
    [J]. CHEMICAL SOCIETY REVIEWS, 2005, 34 (10) : 846 - 857
  • [8] Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule
    Hadjiivanov, KI
    Vayssilov, GN
    [J]. ADVANCES IN CATALYSIS, VOL 47, 2002, 47 : 307 - 511
  • [9] Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
    Kresse, G
    Furthmuller, J
    [J]. PHYSICAL REVIEW B, 1996, 54 (16): : 11169 - 11186
  • [10] NACHTIGALL P, 2007, MICROPOR MESOPOR MAT, DOI DOI 10.1016/J.MICROMESO.2007.1002.1049
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