Liquid-liquid equilibria of water plus 2-butanol plus (Methyl methacrylate or butyl methacrylate or isobutyl methacrylate) at (288.2 and 318.2) K

被引：9

作者：

Chen, Jui-Tang ^{[1
]}

Chang, Hsiu-Ying ^{[1
]}

机构：

[1] Ming Hsin Univ Sci & Technol, Dept Chem Engn, Hsinchu 304, Hsin Feng, Taiwan

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2007年 / 52卷 / 05期

关键词：

D O I：

10.1021/je7002572

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Liquid-liquid equilibrium (LLE) data for the ternary systems water + 2-butanol + methyl methacrylate, butyl metbacrylate, and isobutyl methacrylate were determined at atmospheric pressure and at (288.2 and 318.2) K. The reliability of the experimental tie-line data was determined through the Bachman plots. The experimental data were also compared with the values correlated by the NRTL and UNIQUAC models. Good quantitative agreement was obtained with these models. In general, the average deviations from the UNIQUAC model are slightly smaller than those from the NRTL model.

引用

页码：1950 / 1954

页数：5

共 11 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2]

Bachman I., 1940, IND ENG CHEM ANAL ED, V12, P38, DOI 10.1021/ac50141a013

[3] DEPENDENCE OF THE MUTUAL SOLUBILITIES OF (2-BUTANOL + WATER) UPON PRESSURE AND TEMPERATURE [J].

BOZDAG, O ;

LAMB, JA .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1983, 15 (02) :165-171

[4] Liquid-liquid-solid equilibria for the ternary systems butanols plus water plus sodium chloride or plus potassium chloride [J].

Gomis, V ;

Ruiz, F ;

Asensi, JC ;

Saquete, MD .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (02) :188-191

[5] VAPOR-LIQUID-EQUILIBRIA BY UNIFAC GROUP CONTRIBUTION .5. REVISION AND EXTENSION [J].

HANSEN, HK ;

RASMUSSEN, P ;

FREDENSLUND, A ;

SCHILLER, M ;

GMEHLING, J .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (10) :2352-2355

[6] Liquid-liquid equilibria of ternary mixtures of water+2-propanol with ethyl acetate, isopropyl acetate, or ethyl caproate [J].

Hong, GB ;

Lee, MJ ;

Lin, HM .

FLUID PHASE EQUILIBRIA, 2002, 202 (02) :239-252

[7] Liquid-liquid equilibrium of the water plus citric acid plus short chain alcohol plus tricaprylin system at 298.15 K [J].

Lintomen, L ;

Pinto, RTP ;

Batista, E ;

Meirelles, AJA ;

Maciel, MRW .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (03) :546-550

[8] Measurement of the liquid-liquid equilibria for mixtures of water plus sodium hydroxide plus an alkanol or dimethyl ether using near-infrared spectroscopy [J].

Naicker, PK ;

Sandler, SI ;

Reifsnyder, S .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (02) :191-194

[9] LIQUID-LIQUID EQUILIBRIA OF FUEL OXYGENATE PLUS WATER PLUS HYDROCARBON MIXTURES .1. [J].

PESCHKE, N ;

SANDLER, SI .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (01) :315-320

[10] LOCAL COMPOSITIONS IN THERMODYNAMIC EXCESS FUNCTIONS FOR LIQUID MIXTURES [J].

RENON, H ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1968, 14 (01) :135-+

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