Experimental and theoretical investigation of organic compounds as inhibitors for mild steel corrosion in sulfuric acid medium

被引：353

作者：

Bahrami, M. J. ^{[1
]}

Hosseini, S. M. A. ^{[1
]}

Pilvar, P. ^{[2
]}

机构：

[1] Shahid Bahonar Univ Kerman, Dept Chem, Kerman 76169, Iran

[2] Payame Noor Univ, Dept Chem, Kerman, Iran

来源：

CORROSION SCIENCE | 2010年 / 52卷 / 09期

关键词：

Mild steel; SEM; IR spectroscopy; Acid inhibition; COLD-ROLLED STEEL; 1 M HCL; HYDROCHLORIC-ACID; SCHIFF-BASES; TRIAZOLE DERIVATIVES; MOLECULAR-STRUCTURE; CHEMICAL-STRUCTURE; CHLORIDE SOLUTIONS; QUANTUM-CHEMISTRY; ALUMINUM SURFACE;

D O I：

10.1016/j.corsci.2010.04.024

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Three synthesized organic compounds were tested as corrosion inhibitors for mild steel in sulfuric acid medium by potentiostatic polarization, FTIR spectroscopy and SEM techniques. Quantum chemical parameters were also calculated to characterize adsorption mechanism. Acceptable correlations were obtained between inhibition efficiency and the calculated quantum chemical parameters. It was found that the investigated compounds exhibit a good inhibition effect especially at 8-10 ppm range concentration, which makes them commercially important. The adsorption of inhibitors on the surface obeys Langmuir adsorption isotherm. The values of activation energy and the thermodynamic parameters, such as K-ads, Delta G degrees(ads), Delta H degrees(ads) and Delta S degrees(ads) were calculated. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2793 / 2803

页数：11

共 56 条

[1] 2,3-quinoxalinedione as a novel corrosion inhibitor for mild steel in 1 M HCl [J].

Abboud, Y. ;

Abourriche, A. ;

Saffaj, T. ;

Berrada, M. ;

Charrouf, M. ;

Bennamara, A. ;

Al Himidi, N. ;

Hannache, H. .

MATERIALS CHEMISTRY AND PHYSICS, 2007, 105 (01) :1-5

[2] Rhodanine azosulpha drugs as corrosion inhibitors for corrosion of 304 stainless steel in hydrochloric acid solution [J].

Abdallah, M .

CORROSION SCIENCE, 2002, 44 (04) :717-728

[3] Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid solutions [J].

Ahamad, Ishtiaque ;

Prasad, Rajendra ;

Quraishi, M. A. .

CORROSION SCIENCE, 2010, 52 (03) :933-942

[4] The isoxazolidines: a new class of corrosion inhibitors of mild steel in acidic medium [J].

Ali, SA ;

Saeed, MT ;

Rahman, SU .

CORROSION SCIENCE, 2003, 45 (02) :253-266

[5] Thermodynamic and quantum chemistry characterization of the adsorption of triazole derivatives during Muntz corrosion in acidic and neutral solutions [J].

Allam, Nageh K. .

APPLIED SURFACE SCIENCE, 2007, 253 (10) :4570-4577

[6]

[Anonymous], 1995, J CHIN SOC CORROS PR

[7] The effect of some Schiff bases on the corrosion of aluminum in hydrochloric acid solution [J].

Ashassi-Sorkhabi, H. ;

Shabani, B. ;

Aligholipour, B. ;

Seifzadeh, D. .

APPLIED SURFACE SCIENCE, 2006, 252 (12) :4039-4047

[8] A STUDY OF INHIBITION ACTION OF PROPARGYL ALCOHOL DURING ANODIC-DISSOLUTION OF IRON IN HYDROCHLORIC-ACID [J].

BARTOS, M ;

HACKERMAN, N .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (12) :3428-3433

[9] Evaluating two new synthesized S-N Schiff bases on the corrosion of copper in 15% hydrochloric acid [J].

Behpour, M. ;

Ghoreishi, S. M. ;

Salavati-Niasari, M. ;

Ebrahimi, B. .

MATERIALS CHEMISTRY AND PHYSICS, 2008, 107 (01) :153-157

[10] Electrochemical, theoretical and XPS studies of 2-mercapto-1-methylimidazole adsorption on carbon steel in 1 M HClO4 [J].

Benali, O. ;

Larabi, L. ;

Traisnel, M. ;

Gengembre, L. ;

Harek, Y. .

APPLIED SURFACE SCIENCE, 2007, 253 (14) :6130-6139

← 1 2 3 4 5 6 →