arachno-[Sn8]6 or closo-[Li2Sn8]4-? synthesis and characterization of A4Li2Sn8 (A = Rb, K)

被引：0

作者：

Bobev, S ^{[1
]}

Sevov, SC ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 22期

关键词：

cluster compounds; lithium; solid-state structures; tin; Zintl phases;

D O I：

10.1002/1521-3773(20001117)39:22<4108::AID-ANIE4108>3.0.CO;2-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Square aniiprisms of Sn8/6- (see picture) are present in solid-state structures of the compounds Rb4Li2Sn8 and K4Li2Sn8, which were synthesized from the elements at 400°C. They are the first Zintl phases to contain arachno clusters of main group elements.

引用

页码：4108 / 4110

页数：3

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