A Dual Photochemically Active Molecule Showing Distributable Reactivity Based on Anion-Assisted Coordination Assembly

被引：7

作者：

Zhang, Ya-Jun ^{[1
]}

Chen, Cheng ^{[1
]}

Cai, Li-Xuan ^{[1
]}

Yang, Xiao-Dong ^{[2
]}

Zhang, Jie ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Beijing Inst Technol, Sch Chem & Chem Engn, MOE Key Lab Cluster Sci, Beijing Key Lab Photoelect Electrophoton Convers, Beijing 102488, Peoples R China

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 17期

关键词：

TRANS-CINNAMIC ACIDS; SOLID-STATE; 2+2 CYCLOADDITION; SINGLE-CRYSTAL; PHOTODIMERIZATION; TOPOCHEMISTRY; UV; TRANSFORMATIONS; COMPLEX; LIGHT;

D O I：

10.1021/acs.inorgchem.7b01497

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

photochemically Distributable reactivity of a dual photochemically active molecule functionalized by a carboxyl coordination unit has been achieved based on anion-assisted coordination assembly. The anions induce the photoactive ligand to align at different orientations in three-dimensional metal organic frameworks, thus allowing the supramolecular systems to show photocycloaddition with simultaneous luminescence transformation or undergo photoinduced electron transfer accompanied by coloration decoloration under alternating light and thermal stimuli.

引用

页码：10529 / 10534

页数：6

共 3 条

[1] Anion-assisted Fe(III)-coordination supramolecular systems based on 2,6-diacetylpyridine dihydrazone
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[2] Anion-Coordination-Assisted Assembly of Supramolecular Charge-Transfer Complexes Based on Tris(urea) Ligands
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[3] Platinum(II)-Based Host-Guest Coordination-Driven Supramolecular Co-Assembly Assisted by Pt•••Pt and π-π Stacking Interactions: A Dual-Selective Luminescence Sensor for Cations and Anions
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (02) : 973 - 982

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