Rhodium-catalyzed carbothiolation reaction of 1-alkylthio-1-alkynes

被引：24
作者：
Arisawa, Mieko [1 ]
Igarashi, Yui [1 ]
Tagami, Yoko [1 ]
Yamaguchi, Masahiko [1 ,2 ]
Kabuto, Chizuko [1 ]
机构：
[1] Tohoku Univ, Dept Organ Chem, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan
[2] Tohoku Univ, WPI Res Ctr, Adv Inst Mat Res, Aoba Ku, Sendai, Miyagi 9808578, Japan
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 08期
关键词：
EXCHANGE-REACTION; ALKYNES; DISULFIDES; SULFIDES;
D O I：
10.1016/j.tetlet.2010.12.065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A rhodium complex derived from RhH(PPh(3))(4) and Me(2)PhP catalyzed the carbothiolation reaction of 1-alkylthio-1-alkynes and 1,4-diaryl-1,3-butadiynes giving (Z)-4-alkylthio-4-aryl-3-arylethynyl-3-buten-1-ynes. Terminal alkynes such as 1-decyne and (t-butylthio)acetylene underwent the carbothiolation reaction using a RhH(PPh(3))(4)-dppb catalyst. The reactions proceeded via cis-addition with C-C bond formation at the less hindered acetylene carbon. (C) 2011 Published by Elsevier Ltd.
引用
收藏
页码：920 / 922
页数：3
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