Preparation of Sn-doped CdS/TiO2/conducting polymer fiber composites for efficient photocatalytic hydrogen production under visible light irradiation

被引:6
作者
Ren, Fengmei [1 ]
Ma, Haihong [1 ]
Hu, Wei [1 ,2 ]
Zhou, Zhengfa [1 ]
Xu, Weibing [1 ]
机构
[1] Hefei Univ Technol, Dept Polymer Sci & Engn, Hefei 230009, Anhui, Peoples R China
[2] Anhui Prov Testing Ctr Packaging Prod Qual Superv, Tongcheng 231400, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
catalysts; composites; fibers; WATER; TIO2; NANOPARTICLES; GENERATION; EVOLUTION; NANOCOMPOSITES; NANORODS;
D O I
10.1002/app.42300
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Sn-doped CdS/TiO2 heterojunction was synthesized on the conducting polymer fiber mat by hydrothermal method. The conducting polymer fiber mat was made by electrospinning from polyvinylidene fluoride, styrene-maleic anhydride copolymer, and nano-graphites as conducting fillers. The Sn-doped CdS/TiO2 heterojunction was characterized by XRD, XPS, SEM, TEM, TGA, and UV-Vis absorption spectra. Under simulated solar light irradiation, a combination of Sn-doped CdS/TiO2/conducting polymer was found to be highly efficient for photocatalytic hydrogen evolution from splitting of water. The photocatalytic hydrogen production efficiency was up to 2885 mol h(-1) g(-1)cat. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 42300.
引用
收藏
页数:6
相关论文
共 29 条
[1]   Functional materials by electrospinning of polymers [J].
Agarwal, Seema ;
Greiner, Andreas ;
Wendorff, Joachim H. .
PROGRESS IN POLYMER SCIENCE, 2013, 38 (06) :963-991
[2]   Efficient photocatalytic hydrogen generation by Pt modified TiO2 nanotubes fabricated by rapid breakdown anodization [J].
Antony, Rajini P. ;
Mathews, Tom ;
Ramesh, C. ;
Murugesan, N. ;
Dasgupta, Arup ;
Dhara, S. ;
Dash, S. ;
Tyagi, A. K. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (10) :8268-8276
[3]   Study of the effect of rutile/anatase TiO2 nanoparticles synthesized by hydrothermal route in electrospun PVA/TiO2 nanocomposites [J].
Costa, Rodrigo G. F. ;
Ribeiro, Caue ;
Mattoso, Luiz H. C. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 127 (06) :4463-4469
[4]   Impact of three different TiO2 morphologies on hydrogen evolution by methanol assisted water splitting: Nanoparticles, nanotubes and aerogels [J].
D'Elia, Daniela ;
Beauger, Christian ;
Hochepied, Jean-Francois ;
Rigacci, Arnaud ;
Berger, Marie-Helene ;
Keller, Nicolas ;
Keller-Spitzer, Valerie ;
Suzuki, Yoshikazu ;
Valmalette, Jean-Christophe ;
Benabdesselam, Mourad ;
Achard, Patrick .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (22) :14360-14373
[5]   Preparation of ZnIn2S4/fluoropolymer fiber composites and its photocatalytic H2 evolution from splitting of water using Xe lamp irradiation [J].
Fan, Wen-Juan ;
Zhou, Zheng-Fa ;
Xu, Wei-Bing ;
Shi, Zhi-Feng ;
Ren, Feng-Mei ;
Ma, Hai-Hong ;
Huang, Shuang-Wu .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (13) :6525-6530
[6]   Preparation and characterization of cerium-doped titanium dioxide/ultrahigh-molecular-weight polyethylene porous composites with excellent photocatalytic activity [J].
Gong, Lixiu ;
Zhou, Zhufa ;
Wang, Shumei ;
Wang, Ben .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 129 (03) :1212-1217
[7]   Synthesis, characterization and application of SnSx (x=1, 2) nanoparticles [J].
Gou, XL ;
Chen, J ;
Shen, PW .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 93 (2-3) :557-566
[8]  
Graifer A. Y., 1988, KINET CATAL, V28, P1137
[9]   Preparation and photocatalysis of TiO2-fluoropolymer electrospun fiber nanocomposites [J].
He, Tieshi ;
Zhou, Zhengfa ;
Xu, Weibing ;
Ren, Fengmei ;
Ma, Haihong ;
Wang, Jin .
POLYMER, 2009, 50 (13) :3031-3036
[10]   Heterogeneous photocatalyst materials for water splitting [J].
Kudo, Akihiko ;
Miseki, Yugo .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (01) :253-278