Compositional Variations in Primitive Kimberlite Melts and Entrained Mantle Cargo from a Global Survey of Trace Element Compositions in Kimberlite Olivine

Olivines are the dominant phase of kimberlites and the majority of grains display distinct compositional zoning with xenocrystic cores surrounded by magmatic rims. Previous work has documented large variations in both core and rim major and minor element compositions in kimberlites globally, which has been related to variable entrainment and assimilation of sub-continental lithospheric mantle (SCLM) material. However, there is limited knowledge of trace element variations in olivine from kimberlites and it is unclear whether mantle assimilation has any effect on the trace element composition of kimberlite melts. To fill this gap, we present a global survey of olivine trace element compositions, along with previously reported major and minor element compositions, for samples representing the full spectrum of olivine compositional variations in kimberlites, including samples from the following: Lac de Gras, Canada (Grizzly, Koala); Kimberley, South Africa (Bultfontein, De Beers, Kimberley Big Hole, Wesselton); Kaalvallei, South Africa (New Robinson, Samada); and Alto Paranaiba, Brazil (Limpeza-18, Tres Ranchos-04). Trace element concentrations of olivine cores can discriminate between those derived from the disaggregation of peridotitic material and those related to the megacryst suite. The megacrystic olivine cores exhibit a negative correlation between Al and Mn, which is absent in peridotite-derived cores, and are characterised by high concentrations of temperature-dependent elements (e.g. Al, Na, V) as well as Zn, Ti, and Mn. Following pre-screening of cores for megacrystic and spinel peridotite-derived grains, we applied the Al-in-olivine thermometer to assess the P-T equilibration conditions of cores in equilibrium with garnet and estimate the sampling depth of kimberlite magmas in the lithospheric mantle. Our results are consistent with predominant entrainment of deep lithosphere xenocrysts in highly diamondiferous compared with diamond-poor kimberlites. Temperature-dependent elements display a gradational increase with depth due to higher T with Ca, Cu and, to a lesser extent, Zn and Ti being higher and Mg# being lower towards the base of the SCLM, which is consistent with melt modification of the lower lithosphere. The Zn, Ti, Co, Mn, Li, Al, Cr, Na, and V concentrations of magmatic olivine rims display systematic variations that have a negative correlation with Mg# (whereas Cr is positively correlated). Lac de Gras olivine feature Mg-rich rims (Mg# >90) and low concentrations of these trace elements, whereas the Fe-rich olivine rims (Mg# similar to 85) of the Kaalvallei kimberlites have higher concentrations of these elements, with the Kimberley and Alto Paranaiba kimberlites being intermediate. Direct correlations between average Ti, Zn, Co and Li compositions of olivine cores and rims suggests that the olivine rim (i.e. proxy for primitive melt) variations are related to variable assimilation of metasomatised SCLM and can be effectively used to track the composition of the lithospheric column that is traversed by kimberlite magmas. These observations further imply an intimate link between early proto-kimberlite melt, leading to formation of megacrystic olivine at the base of the SCLM, and the composition of kimberlite melts which entrain and assimilate these products. We conclude that lithospheric mantle assimilation has a major and previously overlooked influence on the trace element composition of kimberlite magmas.