Synchronized collapse and formation of long-period stacking and chemical orders in Mg85Zn6Y9

被引:8
作者
Matsushita, Masafumi [1 ]
Bednarcik, Jozef [2 ]
Sakata, Yuya [1 ]
Akamatsu, Shutaro [1 ]
Nishiyama, Norimasa [2 ]
Michalikoya, Jana [2 ]
Yamasaki, Michiaki [3 ]
Kawamura, Yoshihito [3 ]
机构
[1] Ehime Univ, Dept Mech Engn, Matsuyama, Ehime 7900826, Japan
[2] DESY, D-22607 Hamburg, Germany
[3] Kumamoto Univ, Magnesium Res Ctr, Kumamoto 8608555, Japan
关键词
Long-range ordering; Crystal structure; X-ray diffraction (XRD); ALLOYS; PHASE;
D O I
10.1016/j.physb.2014.12.021
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Phase transformation of the long period stacking order (LPSO) synchronized with the chemical concentration in Mg85Zn6Y9 has been investigated during both heating and cooling via in situ X-ray diffraction analysis. With increasing temperature, above 800 K, 10H-type LPSO phase collapsed firstly. 10H structural modulation collapsed earlier than the chemical modulation of 5 layers per period. The in plane ordering consisted of aligned L1(2)-type clusters vanished before the collapse of chemical and structural modulation of 18R-type LPSO. After, the chemical and structural modulation of 18R-type LPSO show synchronize collapse. During cooling, the 14H-type LPSO emerged in addition to the 18R-type LPSO. The growths of chemical and structural modulation start at the same temperature. After that, the formation of in plane order consisting of aligned L1(2)-type Zn-Y clusters emerged. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:147 / 153
页数:7
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