Significant interferences in the post source decay spectra of ion-gated fullerene and coalesced carbon cluster ions

被引:12
作者
Barrow, MP [1 ]
Drewello, T [1 ]
机构
[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
fullerenes; coalescence; post source decay; delayed ionization; laser desorption/ionization; reflectron time-of-flight mass spectrometry;
D O I
10.1016/S1387-3806(00)00293-1
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Post source decay experiments have been performed with fullerene radical cations and large carbon cluster radical cations, produced from laser desorption/ionization and studied by applying reflectron time-of-flight mass spectrometry. Utilising the wide-spread technique of continuous ion extraction, in conjunction with a deflecting electrode (ion gate) for the selection of ions, the experimental method is carefully evaluated in light of the observation of interfering, artefact signals which have been established as resulting from delayed ionization of fullerenes. (C) 2000 Elsevier Science B.V.
引用
收藏
页码:111 / 125
页数:15
相关论文
共 44 条
  • [1] In-series combination of a magnetic-sector mass spectrometer with a time-of-flight quadratic-field ion mirror
    Andersen, UN
    Colburn, AW
    Makarov, AA
    Raptakis, EN
    Reynolds, DJ
    Derrick, PJ
    Davis, SC
    Hoffman, AD
    Thomson, S
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1998, 69 (04) : 1650 - 1660
  • [2] Matrix-assisted laser-induced gas-phase aggregation of C60 oxides
    Barrow, MP
    Tower, NJ
    Taylor, R
    Drewello, T
    [J]. CHEMICAL PHYSICS LETTERS, 1998, 293 (3-4) : 302 - 308
  • [3] Penta(cyclopentadienyl)-η5-cyclopentadienylmanganesetricarbonyl:: structure and laser-induced conversion to fullerenes
    Barrow, MP
    Cammack, JK
    Goebel, M
    Wasser, IM
    Vollhardt, KPC
    Drewello, T
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 572 (01) : 135 - 139
  • [4] BARROW MP, UNPUB
  • [5] A COMBINED MAGNETIC SECTOR-TIME-OF-FLIGHT MASS-SPECTROMETER FOR STRUCTURAL DETERMINATION STUDIES BY TANDEM MASS-SPECTROMETRY
    BATEMAN, RH
    GREEN, MR
    SCOTT, G
    CLAYTON, E
    [J]. RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1995, 9 (13) : 1227 - 1233
  • [6] Delayed ionization of fullerenes and fullerene derivatives upon laser desorption and surface collision
    Beck, RD
    Weis, P
    Rockenberger, J
    Kappes, MM
    [J]. SURFACE REVIEW AND LETTERS, 1996, 3 (01) : 771 - 775
  • [7] LASER-DESORPTION MASS-SPECTROMETRY OF FULLERENE DERIVATIVES - LASER-INDUCED FRAGMENTATION AND COALESCENCE REACTIONS
    BECK, RD
    WEIS, P
    HIRSCH, A
    LAMPARTH, I
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (39) : 9683 - 9687
  • [8] ENHANCED COALESCENCE UPON LASER-DESORPTION OF FULLERENE OXIDES
    BECK, RD
    STOERMER, C
    SCHULZ, C
    MICHEL, R
    WEIS, P
    BRAUCHLE, G
    KAPPES, MM
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (04) : 3243 - 3249
  • [9] MECHANISTIC ASPECTS OF FULLERENE COALESCENCE UPON ULTRAVIOLET-LASER DESORPTION FROM THIN-FILMS
    BECK, RD
    WEIS, P
    BRAUCHLE, G
    KAPPES, MM
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (01) : 262 - 270
  • [10] Determination of isomeric dibenzo[a,l]pyrene-adenine adducts by six different tandem mass spectrometric experiments
    Byun, J
    Gooden, J
    Ramanathan, R
    Li, KM
    Cavalieri, EL
    Gross, ML
    [J]. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 1997, 8 (09) : 977 - 986