Remote coordination approach for electronic tuning of a rhodium(I)-N-heterocyclic carbene (NHC)-complex

被引：2

作者：

Thenarukandiyil, Ranjeesh ^{[1
]}

Maji, Babulal ^{[1
]}

Choudhury, Joyanta ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Bhopal, Organometall & Smart Mat Lab, Dept Chem, Bhopal 462066, India

来源：

INORGANICA CHIMICA ACTA | 2019年 / 487卷

关键词：

N-heterocyclic carbene (NHC); Remote coordination; Rhodium; Lewis acid; Hydroboration; BIARYL REDUCTIVE ELIMINATION; N-HETEROCYCLIC CARBENES; COMPLEXES; ALKENE; CATALYSIS; LIGHT; POLYMERIZATION; ACTIVATION; EFFICIENCY; CHEMISTRY;

D O I：

10.1016/j.ica.2019.01.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple Lewis acid coordination at the remote binding site installed within a modular N-heterocyclic carbene (NHC) ligated rhodium(I) complex could induce desired electronic influence and thereby enhance the activity of the complex in a model styrene hydroboration reaction.

引用

收藏

页码：419 / 423

页数：5

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