Remote coordination approach for electronic tuning of a rhodium(I)-N-heterocyclic carbene (NHC)-complex

被引：2
作者：
Thenarukandiyil, Ranjeesh [1 ]
Maji, Babulal [1 ]
Choudhury, Joyanta [1 ]
机构：
[1] Indian Inst Sci Educ & Res Bhopal, Organometall & Smart Mat Lab, Dept Chem, Bhopal 462066, India
来源：
INORGANICA CHIMICA ACTA | 2019年 / 487卷
关键词：
N-heterocyclic carbene (NHC); Remote coordination; Rhodium; Lewis acid; Hydroboration; BIARYL REDUCTIVE ELIMINATION; N-HETEROCYCLIC CARBENES; COMPLEXES; ALKENE; CATALYSIS; LIGHT; POLYMERIZATION; ACTIVATION; EFFICIENCY; CHEMISTRY;
D O I：
10.1016/j.ica.2019.01.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple Lewis acid coordination at the remote binding site installed within a modular N-heterocyclic carbene (NHC) ligated rhodium(I) complex could induce desired electronic influence and thereby enhance the activity of the complex in a model styrene hydroboration reaction.
引用
收藏
页码：419 / 423
页数：5
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