Electrochemical synthesis and a redetermination of Ni(acac)2(H2O)2 • H2O

被引：6
|
作者：
Zhou, XF [1 ]
Han, AJ
Chu, DB
Huang, ZX
机构：
[1] Anhui Normal Univ, Inst Organ Chem, Wuhu 241000, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801016208
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, bis(acetylacetonato)diaquanickel(II) monohydrate, [Ni(C5H7O2)(2)(H2O)2)].H2O, was easily synthesized in high yield by electrochemical dissolution of nickel metal in an acetylacetone and ethanol solution via direct hydrolysis of the electrolyte solution at a temperature of 333 K. The crystal structure shows octahedral coordination of nickel with two trans aqua ligands. An uncoordinated water molecule engages in hydrogen bonding.
引用
收藏
页码：M506 / M508
页数：3
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