Biobased Plasticizers from Carbohydrate-Derived 2,5-Bis(hydroxymethyl)furan

被引：30
作者：
Howell, Bob A. [1 ]
Lazar, Simone T. [1 ]
机构：
[1] Cent Michigan Univ, Dept Chem & Biochem, Ctr Applicat Polymer Sci, Mt Pleasant, MI 48859 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2019年 / 58卷 / 03期
关键词：
PVC MEDICAL DEVICES; FLAME RETARDANTS; POLY(VINYL CHLORIDE); TARTARIC ACID; ESTERS; EXPOSURE; ISOSORBIDE; BIOMASS; ASSOCIATION; CONVERSION;
D O I：
10.1021/acs.iecr.8b05442
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
As potential replacements for phthalate plasticizers, a series of esters of biobased 2,5-bis(hydroxymethyl)furan has been synthesized and fully characterized using spectroscopic and thermal methods. These materials are fully compatible with PVC and display a good plasticizing effect, comparable to that of common phthalate plasticizers. The presence of these materials does not diminish the thermal stability of the polymer, and they display a low migratory potential. These compounds would seem to represent attractive biobased alternatives to traditional phthalate esters for the plasticization of PVC.
引用
收藏
页码：1222 / 1228
页数：7
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