New organic dispersions of conducting polymers using polymeric ionic liquids as stabilizers

被引：63

作者：

Marcilla, R ^{[1
]}

Ochoteco, E ^{[1
]}

Pozo-Gonzalo, C ^{[1
]}

Grande, H ^{[1
]}

Pomposo, JA ^{[1
]}

Mecerreyes, D ^{[1
]}

机构：

[1] Ctr Electrochem Technol CIDETEC, E-20009 San Sebastian, Spain

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 14期

关键词：

conducting polymers; dispersions; ionic liquids; phase transfer; polyelectrolytes;

D O I：

10.1002/marc.200500250

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polypyrrole (PPy), polyaniline (PANI), and poly(ethylenedioxythiophene) (PEDOT) aqueous dispersions were prepared by polymerizing the corresponding monomer in the presence of a polymeric ionic liquid (PIL), poly(1-vinyl-3-ethylimidazolium bromide). By addition of bispentafluoroethanesulfonimide lithium salt, the PIL stabilizer becomes hydrophobic and precipitates in water and traps the conducting polymer microparticles inside. The dispersion of the recovered powders in organic solvents leads to organic conducting dispersions. After casting the organic dispersions, hydrophobic films with electrical conductivity values as high as 0.1 S (.) cm(-1) were obtained.

引用

页码：1122 / 1126

页数：5

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