Highly ordered π-extended discotic liquid-crystalline triindoles

被引：35
|
作者：
Garcia-Frutos, Eva M. [1 ,2 ]
Omenat, Ana [2 ]
Barbera, Joaquin [2 ]
Luis Serrano, Jose [2 ]
Gomez-Lor, Berta [1 ]
机构：
[1] CSIC, Inst Ciencias Mat Madrid, E-28049 Madrid, Spain
[2] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Organ, E-50009 Zaragoza, Spain
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 19期
关键词：
CHARGE-TRANSPORT; SELF-ASSOCIATION; TRIAZATRUXENE;
D O I：
10.1039/c0jm04395h
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
New pi-extended discotic liquid crystals based on heptacyclic triindole have been synthesized and their mesomorphic behaviour investigated. The synthesis of pi-extended compounds was carried out by oxidative cyclodehydrogenation of differently substituted star-shaped hexaaryltriindoles to afford the planar derivatives with an extended core. Extending the conjugation in these materials results in a significant increase in the order and range of the mesophases. The influence of the peripherally attached groups in the mesomorphic and electronic properties offers a great opportunity to further tune the properties of these compounds intended to their incorporation in devices.
引用
收藏
页码：6831 / 6836
页数：6
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