[Pd{CH2C(O)Me}Cl]n, a key product for the synthesis of acetonylpalladium(II) complexes

被引：59
作者：
Vicente, J
Arcas, A
Fernández-Hernández, JM
Bautista, D
机构：
[1] Univ Murcia, Fac Quim, Dept Quim Inorgan, Grp Quim Organomet, E-30071 Murcia, Spain
[2] Univ Murcia, SACE, E-30071 Murcia, Spain
来源：
ORGANOMETALLICS | 2001年 / 20卷 / 13期
关键词：
transphobia;
D O I：
10.1021/om0101036
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Hg{CH2C(O)Me}(2)] reacts with [PdCl2(MeCN)(2)] (1:1) or with (Me4N)(2)[Pd2Cl6] (2:1) to give [Pd{CH2C(O)Me}Cl](n), which can be used to prepare a variety of acetonyl complexes. Thus, by reacting it; with the appropriate ligands, complexes [Pd{CH2C(O)Me}I](n), [Pd{CH2C(O)-Me}CIL2] [L-2 = N,N,N 'N ' -tetramethylethylenediamine, 2,2 ' -bipyridine, 4,4 '-(Bu-t)(2)-2,2 ' -bipyridine, 1,10-phenathroline; L = PPh3, dimethyl sulfoxide (dmso)], [Pd-2{CH2C(O)Me}{mu-kappa (2)-C,O-CH2C(O)Me}(mu -Cl)Cl(dmso)(2)], or [Pd-2{CH2C(O)Me}(2)(mu -Cl)(2)(tetrahydrothiophene)(2)] can be obtained. The crystal structures of the last two complexes and that of [Hg{CH2C(O)Me}(2)] have been determined by X-ray crystallography.
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页码：2767 / 2774
页数：8
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