Recent Advances in the Catalytic Asymmetric Reactions of Oxaziridines

被引：12

作者：

Ren, Qiao ^{[1
]}

Yang, Wen ^{[1
]}

Lan, Yunfei ^{[1
]}

Qin, Xurong ^{[1
]}

He, Youzhou ^{[2
]}

Yuan, Lujiang ^{[1
]}

机构：

[1] Southwest Univ, Key Lab Luminescent & Real Time Analyt Chem, Minist Educ, Coll Pharmaceut Sci, Chongqing 400715, Peoples R China

[2] Chongqing Technol & Business Univ, Coll Environm & Resources, Chongqing 400067, Peoples R China

来源：

MOLECULES | 2018年 / 23卷 / 10期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

oxaziridines; asymmetric catalysis; oxidation; amination; aminohydroxylation; KETOMALONATE-DERIVED OXAZIRIDINE; FORMAL 3+2 CYCLOADDITION; OXYGEN-ATOM TRANSFER; C-H HYDROXYLATION; ELECTROPHILIC AMINATION; ENANTIOSELECTIVE SYNTHESIS; ALPHA-HYDROXYLATION; MEDIATED OXIDATION; SULFIDES; CHEMISTRY;

D O I：

10.3390/molecules23102656

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Oxaziridines have emerged as powerful and elegant oxygen- and nitrogen-transfer agents for a broad array of nucleophiles, due to the remarkably high and tunable reactivities. However, the asymmetric catalysis involving oxaziridines is still in its infancy. Herein, this review aims to examine recent advances in the catalytic asymmetric transformations of oxaziridines, including oxidation, amination, cycloaddition and deracemization.

引用

页数：17

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