Bromidotricarbonyl[4-iodo-N-(pyridin-2-ylmethylidene)aniline-κ2N,N′] rhenium(I)

被引：5

作者：

Dehghanpour, Saeed ^{[1
]}

Mahmoudi, Ali ^{[1
]}

机构：

[1] Islamic Azad Univ, Dept Chem, Karaj Branch, Karaj, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

SPECTRAL CHARACTERIZATION; COMPLEXES;

D O I：

10.1107/S1600536810037104

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [ReBr(C12H9IN2)(CO)(3)], the coordination geometry of the Re-I ion is a distorted fac-ReC3BrN2 octahedron, arising from the N, N'-bidentate ligand, a bromide ion and a facial arrangement of three carbonyl ligands. The dihedral angle between the aromatic rings in the 4-iodo-N-(pyridin-2-ylmethylidene)aniline ligand is 46.2 (3)degrees. The bromide ion and its corresponding trans CO molecule are disordered over two sets of sites in a 0.966 (3): 0.034 (3) ratio.

引用

页码：M1335 / U1492

页数：8

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