Corrosion inhibition of mild steel by Calotropis procera leaves extract in a CO2 saturated sodium chloride solution

被引:34
作者
Ibrahim, Taleb [1 ]
Gomes, Elron [1 ]
Obot, Ime B. [2 ]
Khamis, Mustafa [3 ]
Abou Zour, Mohamed [4 ]
机构
[1] Amer Univ Sharjah, Dept Chem Engn, Sharjah, U Arab Emirates
[2] King Fahd Univ Petr & Minerals, Res Inst, Ctr Res Excellence Corros, Dhahran, Saudi Arabia
[3] Amer Univ Sharjah, Dept Chem Biol & Environm Sci, Sharjah, U Arab Emirates
[4] GE Water & Proc Technol, Dubai, U Arab Emirates
关键词
Steel corrosion; molecular simulation; electrochemical techniques; adsorption; polarization; natural corrosion inhibitor; CARBON-DIOXIDE CORROSION; AMPHIPHILIC AMIDO-AMINE; ACID-MEDIUM; TEMPERATURE; PERFORMANCE; DERIVATIVES; IMIDAZOLINE; ADSORPTION; EFFICIENCY;
D O I
10.1080/01694243.2016.1185229
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The Calotropis procera leaves extract (CPLE) was investigated as a corrosion inhibitor for mild steel in a CO2-saturated 3.5 wt% NaCl solution using various electrochemical techniques. The results show that the CPLE is an effective inhibitor with inhibition efficiency of 80% using 50 ppm. Polarization studies show that the CPLE acts as a mixed inhibitor, and the adsorption of CPLE follows Langmuir adsorption isotherm. Molecular dynamics simulations reveal that the presence of N, O in the CPLE as well as p-electron systems coupled with high adsorption energies of interaction of the CPLE with steel are responsible for corrosion inhibition performance.
引用
收藏
页码:2523 / 2543
页数:21
相关论文
共 43 条
[1]  
Buchweishaija J., 2009, Tanz. J. Sci, V35, P77
[2]   The effect of temperature and concentration on the corrosion inhibition mechanism of an amphiphilic amido-amine in CO2 saturated solution [J].
Desimone, M. P. ;
Gordillo, G. ;
Simison, S. N. .
CORROSION SCIENCE, 2011, 53 (12) :4033-4043
[3]   Amphiphilic amido-amine as an effective corrosion inhibitor for mild steel exposed to CO2 saturated solution: Polarization, EIS and PM-IRRAS studies [J].
Desimone, M. P. ;
Grundmeier, G. ;
Gordillo, G. ;
Simison, S. N. .
ELECTROCHIMICA ACTA, 2011, 56 (08) :2990-2998
[4]   THEORY OF ORGANIC CORROSION INHIBITORS - ADSORPTION AND LINEAR FREE ENERGY RELATIONSHIPS [J].
DONAHUE, FM ;
NOBE, K .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1965, 112 (09) :886-&
[5]  
Farelas F, 2010, INT J ELECTROCHEM SC, V5, P797
[6]   Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review [J].
Finsgar, Matjaz ;
Jackson, Jennifer .
CORROSION SCIENCE, 2014, 86 :17-41
[7]   Corrosion Inhibition Studies of Mild Steel in Acid Medium Using Musa Acuminata Fruit Peel Extract [J].
Gunavathy, N. ;
Murugavel, S. C. .
E-JOURNAL OF CHEMISTRY, 2012, 9 (01) :487-495
[8]   Theoretical studies of three triazole derivatives as corrosion inhibitors for mild steel in acidic medium [J].
Guo, Lei ;
Zhu, Shanhong ;
Zhang, Shengtao ;
He, Qiao ;
Li, Weihua .
CORROSION SCIENCE, 2014, 87 :366-375
[9]   The effect of Thyme leaves extract on corrosion of mild steel in HCl [J].
Ibrahim, Taleb ;
Alayan, Hisham ;
Al Mowaqet, Yasmin .
PROGRESS IN ORGANIC COATINGS, 2012, 75 (04) :456-462
[10]  
Ibrahim T, 2011, INT J ELECTROCHEM SC, V6, P5357