METHODOLOGY FOR THE STUDY OF THE DOLOMITE POROSITY IN ESSAY OF INTERRUPTED SULFATION

被引:6
作者
Avila, Ivonete [1 ]
Crnkovic, Paula M. [1 ]
Milioli, Fernando E. [1 ]
机构
[1] Univ Sao Paulo, Escola Engn Sao Carlos, Dept Engn Mecan, BR-13566590 Sao Carlos, SP, Brazil
来源
QUIMICA NOVA | 2010年 / 33卷 / 08期
关键词
sulfation; limestone; porosimetry; CALCIUM-BASED SORBENTS; SULFUR-DIOXIDE; SO2; REACTIVITY; LIMESTONE; KINETICS; SORPTION; CAPTURE; CACO3; CAO;
D O I
10.1590/S0100-40422010000800021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
METHODOLOGY FOR THE STUDY OF THE DOLOMITE POROSITY IN ESSAY OF INTERRUPTED SULFATION. The aim of this work is to propose a methodology to evaluate the evolution of the pore blockage of limestone during the sulfation reaction. The experiments were performed for a national limestone (dolomite) with average particle size of 545 mu m in interrupted sulfation tests were conducted at seven different times and at three different temperatures of the process. The empirical data were obtained from porosimetry tests to establish BET surface area, volume and average size of pore and distribution of pore sizes of the sulfated samples. Thermogravimetric tests were performed to evaluate the preparation methodology of the samples used in the porosimetry tests.
引用
收藏
页码:1732 / U149
页数:9
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