Trace Metal Content and Health Risk Assessment of PM10 in an Urban Environment of Leon, Mexico

被引:15
作者
Ceron Breton, Julia Griselda [1 ]
Ceron Breton, Rosa Maria [1 ]
Espinosa Guzman, Alberto Antonio [2 ]
Guarnaccia, Claudio [3 ]
Martinez Morales, Stephanie [1 ]
Lara Severino, Reyna del Carmen [1 ]
Rangel Marron, Marcela [1 ]
Hernandez Lopez, Guadalupe [1 ]
Carranco Lozada, Simon Eduardo [4 ]
Kahl, Jonathan D. W. [5 ]
Pech Pech, Ildefonso Esteban [6 ]
Ramirez Lara, Evangelina [7 ]
Espinosa Fuentes, Maria de la Luz [8 ]
机构
[1] Univ Autonoma Carmen, Calle 56 4 Esq Ave Concordia, Ciudad del Carmen 24180, Campeche, Mexico
[2] Conacyt Univ Autonoma Campeche, Av Heroe de Nacozari 480,Campus 6 Invest, San Francisco De Campech 24070, Campeche, Mexico
[3] Univ Salerno, Civil Engn Dept, Via Giovanni Paolo 2, I-13284084 Fisciano, SA, Italy
[4] Inst Politecn Nacl, CECyT 17 Leon Blvd Caliope 1055, Guanajuato 7738, Mexico
[5] Univ Wisconsin, Dept Math Sci, POB 413, Milwaukee, WI 53201 USA
[6] Univ Autonoma Campeche, Ctr Invest Corros, Av Heroe De Nacozari 480,Campus 6 Invest, San Francisco Campeche 24070, Campeche, Mexico
[7] Univ Autonoma Nuevo Leon, Fac Ciencias Quim, Ave Univ S-N Cd Univ, San Nicolas De Los Garza 66455, Nuevo Leon, Mexico
[8] Univ Nacl Autonoma Mexico, Ctr Ciencias Atmosfera, Invest Cient S-N, Ciudad De Mexico 04510, Cdmx, Mexico
关键词
PM10; heavy metals; risk analysis; SEM-EDS; enrichment factor; LONG-RANGE TRANSPORT; PARTICULATE MATTER; HEAVY-METALS; CHEMICAL-COMPOSITION; AIR-POLLUTION; IDENTIFICATION; AEROSOLS; EXPOSURE; PM2.5; SITE;
D O I
10.3390/atmos10100573
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Trace metal concentrations in PM10 were measured in an urban-industrial site in Leon, Mexico in three different seasons. PM10 were collected in quartz fiber filters of 47 mm diameter using low volume equipment operating with a controlled flow of 5 L min(-1) over 24 h. Mass concentrations were gravimetrically determined and it was found that PM10 samples showed values in excess of the Mexican standard and the established values by WHO during cold dry and warm dry seasons. Morphology of selected particles was studied by SEM-EDS analysis, and the elemental composition was determined. Collected samples were analyzed by atomic absorption spectrometry in order to quantify ambient air concentrations of some trace metals (Cu, Co, Zn, Cd, Fe, Mg, and Mn). Median concentrations of trace metals showed the maximum value for iron (3.079 mu gm(-3)) and the minimum value for Cd (0.050 mu gm(-3)) over the entire period. From the meteorological analysis, it was found that sources located SW and ESE of the sampling site contributed to the levels of trace metals in PM10 in the studied site. The health risk assessment found that the population of Leon is at increased lifetime risk of experiencing cancer because of exposure to these concentrations of PM10 and their trace metal content.
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页数:18
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