Solvothermal synthesis, structure, and luminescence of a 3-D Cd(II) complex assembled with biphenyl-2,5,2′,5′-tetracarboxylic acid involving in situ ligand reaction

被引：13

作者：

Guo, Shengqi ^{[1
]}

Tian, Dan ^{[1
]}

Luo, Yuhui ^{[1
]}

Zhang, Hong ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 02期

关键词：

Trinuclear Cd(II) unit; Amidation reaction; Topology; Photoluminescent; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES;

D O I：

10.1080/00958972.2011.652099

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3-D metal-organic framework [Cd-3(L)(2)(DMF)(2)]center dot 2H(2)O center dot 2DMF (1) (H3L=2-(dimethylcarbamoyl) biphenyl-5,2',5'-tricarboxylic acid, DMF = N,N-dimethylformamide) with trinuclear Cd(II) units has been prepared. Complex 1 is a (3, 6)-connected (4(2) . 6)(2)(4(4) . 6(2) . 8(8) . 10) coordination net, which results from the solvothermal in situ formation of a new asymmetric ligand, 2-(dimethylcarbamoyl) biphenyl-5,2',5'-tricarboxylic acid (H3L), through amidation of biphenyl-2,5,2',5;-tetracarboxylic acid (H(4)bptc). Additionally, the luminescence of 1 has been investigated.

引用

页码：308 / 315

页数：8

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