Combination of ring-opening polymerization and "click'' chemistry towards functionalization of aliphatic polyesters

被引：193

作者：

Riva, R ^{[1
]}

Schmeits, P ^{[1
]}

Stoffelbach, F ^{[1
]}

Jérôme, C ^{[1
]}

Jérôme, R ^{[1
]}

Lecomte, P ^{[1
]}

机构：

[1] Univ Liege, Ctr Educ & Res Macromol, B6A St Tilman, B-4000 Liege, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 42期

关键词：

D O I：

10.1039/b510282k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly( ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 degrees C), such that the aliphatic polyesters are not degraded, including even poly( lactide) which is very sensitive to attack by weak nucleophiles.

引用

页码：5334 / 5336

页数：3

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