Electro-conversion of cumene into acetophenone using boron-doped diamond electrodes

被引：3

作者：

Kitano, Mana ^{[1
]}

Saitoh, Tsuyoshi ^{[2
]}

Nishiyama, Shigeru ^{[1
]}

Einaga, Yasuaki ^{[1
]}

Yamamoto, Takashi ^{[1
]}

机构：

[1] Keio Univ, Dept Chem, 3-14-1 Hiyoshi, Yokohama 2238522, Japan

[2] Univ Tsukuba, Int Inst Integrat Sleep Med WPI IIIS, 1-1-1 Tennodai, Tsukuba 3058575, Japan

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 18卷

关键词：

aromatic alkyl; boron-doped diamond electrode; electrosynthesis; oxidation; ENGINEERING ASPECTS; OXIDATION;

D O I：

10.3762/bjoc.18.119

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A straightforward electro-conversion of cumene into acetophenone has been reported using boron-doped diamond (BDD) elec-trodes. This particular conversion is driven by the addition reaction of a cathodically generated hydroperoxide anion to an anodi-cally generated cumyl cation, where the BDD's wide potential window enables the direct anodic oxidation of cumene into the cumyl cation. Since electricity is directly employed as the oxidizing and reducing reagents, the present protocol is easy to use, suit-able for scale-up, and inherently safe.

引用

页码：1154 / 1158

页数：5

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