Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN•

被引：38

作者：

Alberola, A ^{[1
]}

Clarke, CS ^{[1
]}

Haynes, DA ^{[1
]}

Pascu, SI ^{[1
]}

Rawson, JM ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 37期

关键词：

D O I：

10.1039/b508371k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sterically protected dithiadiazolyl radical (F3C)(3)C6H2-CNSSNcenter dot (1) crystallises in two polymorphs: 1 alpha, comprised of monomeric units and 1 beta, containing a mixture of both pi*-pi* dimers and S = 1/2 monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.

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页码：4726 / 4728

页数：3

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