Synthesis and free-radical polymerization of water-soluble acrylamide monomers

被引：9

作者：

Gur'eva, L. L. ^{[1
]}

Tkachuk, A. I. ^{[1
]}

Estrin, Ya. I. ^{[1
]}

Komarov, B. A. ^{[1
]}

Dzhavadyan, E. A. ^{[1
]}

Estrina, G. A. ^{[1
]}

Bogdanova, L. M. ^{[1
]}

Surkov, N. F. ^{[1
]}

Rozenberg, B. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Mascow Oblast, Russia

来源：

POLYMER SCIENCE SERIES A | 2008年 / 50卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0965545X08030061

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Water-soluble acrylamide monomers N-(hydroxymethyl)acrylamide, N-(hydroxymethyl)methacrylamide, N,N-diethanolacrylamide, N,N-diethanolmethacrylamide, N,N-methylethanolacrylamide, and N,N-methylethanolmethacrylamide have been synthesized and characterized. The kinetics and thermodynamics of the free-radical polymerization of these monomers and of the model compounds N-isopropylacrylamide and acrylamide have been studied by the methods of isothermal and scanning calorimetry. The structure and the solubility of the said polymers in water and organic solvents have been investigated and their molecular-mass characteristics and temperatures of glass transition (T-g) and melting (T-m) have been examined by DSC, liquid chromatography, H-1 NMR and IR spectroscopy, and chemical analysis of functional groups. Hydrogels and amphiphilic network polymers based on acrylamide monomers have been prepared and characterized.

引用

页码：283 / 290

页数：8

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